Synthesis and Investigations of Chiral NNO Type Copper(II) Coordination Polymers
Научная публикация
| Общая информация |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Журнал |
ChemistrySelect
, E-ISSN: 2365-6549
|
| Вых. Данные |
Год: 2018,
Том: 3,
Номер: 2,
Страницы: 653-656
Страниц
: 3
DOI:
10.1002/slct.201702689
|
| Ключевые слова |
Aldol reaction, Coordination polymers, Copper, N,O ligands, Tridentate ligands |
| Авторы |
Larionov Vladimir A.
1,2
,
Yashkina Lidiya V.
1
,
Smol’yakov Alexander F.
1
,
Zubavichus Yan V.
3
,
Babievsky Kirill K.
1
,
Akat’yev Nikolay V.
1
,
Титов Алексей А.
1
,
Belokon Yuri N.
1
,
Maleev Victor I.
1
|
| Организации |
| 1 |
A. N. Nesmeyanov Institute of Organoelement Compounds
Russian Academy of Sciences
|
| 2 |
Department of Inorganic Chemistry
People’s Friendship University of Russia (RUDN University)
|
| 3 |
National Research Center ‘‘Kurchatov Institute’’
|
|
Информация о финансировании (3)
|
1
|
Министерство образования и науки Российской Федерации
|
|
|
2
|
Российский фонд фундаментальных исследований
|
15-03-05648
|
|
3
|
Президиум РАН
|
38
|
Herein, we report the synthesis and characterizations of chiral copper(II) coordination polymers (CPs) based on Schiff base of (S)‐2‐aminomethylpyrrolidine and salicylaldehyde derivatives. Single crystal X‐ray analysis showed that copper(II) complex is 1D CP, with the repeating units LCu‐OAc (L=ligand) organized in a perpendicular manner, where the copper(II) atoms are six‐coordinated and have a distorted octahedral geometry. Also complex with chlorine counter ion having unusual dimeric structure was synthesized and characterized. It was demonstrated that CPs catalyze the enantioselective Henry reaction with up to 78% ee.