Effect of Lattice Strain on the Dehydriding Kinetics in Nanoparticles Научная публикация
Журнал |
The Journal of Physical Chemistry C
ISSN: 1932-7447 , E-ISSN: 1932-7455 |
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Вых. Данные | Год: 2009, Том: 113, Номер: 17, Страницы: 6894-6897 Страниц : 4 DOI: 10.1021/jp901552n | ||||
Ключевые слова | HYDROGEN STORAGE; DESORPTION-KINETICS; HYDRIDE FORMATION; METAL-HYDRIDES; PHASE; ABSORPTION; DIFFUSION; SURFACE; ALLOYS; MODEL | ||||
Авторы |
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Организации |
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Реферат:
Hydriding or dehydriding of metal nanoparticles is accompanied by the lattice strain. Using an exactly solvable model describing the strain distribution, we show the effect of strain on the dehydriding kinetics controlled by hydrogen desorption from the surface layer. The strain is found to suppress the desorption rate primarily during the initial stage of the kinetics, and this stage may be relatively slow. The corresponding nonlinear kinetic features are observed in experiments.
Библиографическая ссылка:
Zhdanov V.P.
, Kasemo B.
Effect of Lattice Strain on the Dehydriding Kinetics in Nanoparticles
The Journal of Physical Chemistry C. 2009. V.113. N17. P.6894-6897. DOI: 10.1021/jp901552n WOS Scopus РИНЦ
Effect of Lattice Strain on the Dehydriding Kinetics in Nanoparticles
The Journal of Physical Chemistry C. 2009. V.113. N17. P.6894-6897. DOI: 10.1021/jp901552n WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 20 февр. 2009 г. |
Принята к публикации: | 22 мар. 2009 г. |
Опубликована online: | 8 апр. 2009 г. |
Опубликована в печати: | 30 апр. 2009 г. |
Идентификаторы БД:
Web of science | WOS:000265529700004 |
Scopus | 2-s2.0-67049086637 |
РИНЦ | 13610921 |
Chemical Abstracts | 2009:417024 |
Chemical Abstracts (print) | 150:520518 |
OpenAlex | W2093830330 |