Colloidal FeIII, MnIII, CoIII and CuII Hydroxides Stabilized by Starch as Catalysts of Water Oxidation Reaction with One Electron Oxidant Ru(bpy)33+ | Sciact - CRIS-система Института катализа

Colloidal FeIII, MnIII, CoIII and CuII Hydroxides Stabilized by Starch as Catalysts of Water Oxidation Reaction with One Electron Oxidant Ru(bpy)33+ Научная публикация

Журнал

ChemPhysChem
ISSN: 1439-4235 , E-ISSN: 1439-7641

Вых. Данные

Год: 2019, Том: 20, Номер: 3, Страницы: 410-421 Страниц : 12 DOI: 10.1002/cphc.201800957

Ключевые слова

water splitting; one-electron oxidants; transition metal hydroxides; catalytic activity; oxygen evolution reaction

Авторы

Chikunov Andrei S. ¹ , Taran Oxana P. ^1,2,3 , Pyshnaya Inna A. ⁴ , Parmon Valentin N. ¹

Организации

1	Boreskov Institute of Catalysis (BIC SB RAS) 630090, Novosibirsk, Lavrentieva ave. 5 (Russian Federation)
2	Institute of Chemistry and Chemical Technilogy SB RAS (ICCT SB RAS) 660036, Krasnoyarsk, Akademgorodok st. 50-24 (Russian Federation)
3	Siberian Federal University 660041, Krasnoyarsk, Svobodny ave. 79 (Russian Federation)
4	Institute of Chemical Biology and Fundamental Medicine SB RAS (ICBFM SB RAS)

Информация о финансировании (3)

1	Федеральное агентство научных организаций России	0303-2016-0012 (V.47.1.4.)
2	Российский фонд фундаментальных исследований	15-29-01275
3	Федеральное агентство научных организаций России	0356-2016-0503

Colloidal catalysts for water oxidation to dioxygen, which are stable on storage and under the reaction conditions, are synthesized based on CoIII, MnIII, FeIII and CuII hydroxides. Stabilization of the colloids with dextrated starch allows the process of hydroxide ageing to be stopped at the stage of the formation of primary nuclei (ca. 2–3 nm from TEM data). Molecular mechanics and DLS studies indicate the core‐shell type structure of the catalysts, where the hydroxide core is stabilized by the molecular starch network (ca. 5–7 nm). The colloidal catalysts are highly effective to oxidation of water with one electron oxidant Ru(bpy)33+ at pH 7 to 10. The influence of pH, catalyst concentration and buffer nature on the oxygen yield is studied. The maximal yields are 72, 53 and 78 % over Fe‐, Mn‐ and Co‐containing catalysts, respectively, and TON are 7.8; 54 and 360, respectively. The Cu‐containing catalyst is poorly effective to water oxidation (the maximal yield is 28 % O2). The developed catalysts are of interest for kinetic studies of the mechanism of water oxidation using stopped‐flow technique and as precursors for anchoring nanosize hydroxides onto various supports in order to develop biomimetic systems for artificial photosynthesis.

Chikunov A.S. , Taran O.P. , Pyshnaya I.A. , Parmon V.N.
Colloidal FeIII, MnIII, CoIII and CuII Hydroxides Stabilized by Starch as Catalysts of Water Oxidation Reaction with One Electron Oxidant Ru(bpy)33+

ChemPhysChem. 2019. V.20. N3. P.410-421. DOI: 10.1002/cphc.201800957 WOS Scopus РИНЦ

Полный текст от издателя

Поступила в редакцию:	12 окт. 2018 г.
Принята к публикации:	6 дек. 2018 г.
Опубликована online:	6 дек. 2018 г.
Опубликована в печати:	4 февр. 2019 г.

Web of science	WOS:000457714700010
Scopus	2-s2.0-85059583212
РИНЦ	38700991
Chemical Abstracts	2019:41225
PMID (PubMed)	30520572
OpenAlex	W2904586953

БД	Цитирований
Scopus	3
Web of science	3
РИНЦ	2
OpenAlex	3