Mechanochemical Synthesis of Nanocrystalline Nickel–Molybdenum Compounds and Their Morphology and Application in Catalysis: II. Effect of Mechanochemical Activation Parameters — Process Power Density and Exposure Time — on the Composition and Structure of Nickel–Molybdenum Compounds
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Переводная
|
| Журнал |
Kinetics and Catalysis
ISSN: 0023-1584
, E-ISSN: 1608-3210
|
| Вых. Данные |
Год: 2014,
Том: 55,
Номер: 1,
Страницы: 121-129
Страниц
: 9
DOI:
10.1134/S0023158414010042
|
| Ключевые слова |
SULFIDE CATALYSTS |
| Авторы |
Knyazheva O.A.
1
,
Baklanova O.N.
1
,
Lavrenov A.V.
1
,
Drozdov V.A.
1,2
,
Leont’eva N.N.
1
,
Vasilevich A.V.
1
,
Shilova A.V.
1
,
Likholobov V.A.
1,2
|
| Организации |
| 1 |
Institute of Hydrocarbon Processing, Siberian BranchRussian Academy of SciencesOmskRussia
|
| 2 |
Omsk State Technical UniversityOmskRussia
|
|
The effect of mechanochemical activation parameters—process power density and the time of treatment of a mixture of nickel hydroxocarbonate NiCO3 · 2Ni(OH)2 · nH2O and ammonium paramolybdate (NH4)6Mo7O24 · 4H2O —on the phase composition, specific surface area, and morphology of mechanically activated products at different Ni : Mo atomic ratios was studied. It was found that, at a mechanochemical activation process power density of 6.2 W/g, layered transition metal molybdates (LTM compounds) with different amounts of crystal water were the constituents of the products, whereas the products mechanically activated at a power density of 28.0 W/g contained a mixture of LTM compounds and heteropoly compounds with the Anderson structure regardless of activation time.