Study of Pt/MgAlOx Catalysts in n-Decane Dehydrogenation
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Переводная
|
| Журнал |
Kinetics and Catalysis
ISSN: 0023-1584
, E-ISSN: 1608-3210
|
| Вых. Данные |
Год: 2015,
Том: 56,
Номер: 5,
Страницы: 655-662
Страниц
: 8
DOI:
10.1134/s0023158415050018
|
| Ключевые слова |
aluminum–magnesium layered hydroxides platinum catalysts n-decane dehydrogenation |
| Авторы |
Belskaya O.B.
1,2
,
Stepanova L.N.
1
,
Gulyaeva T.I.
1
,
Golinskii D.V.
![]()
1
,
Belyi A.S.
1,2
,
Likholobov V.A.
1,2
|
| Организации |
| 1 |
Institute of Hydrocarbons Processing, Siberian BranchRussian Academy of SciencesOmskRussia
|
| 2 |
Omsk State Technical University, Omsk, Russia
|
|
Информация о финансировании (1)
|
1
|
Совет по грантам Президента Российской Федерации
|
НШ-3631.2014.3
|
The properties of Pt/MgAlO x catalysts based on aluminum–magnesium layered hydroxides have been investigated in n-decane dehydrogenation. The n-decene formation selectivity depends on the Mg/Al ratio in the support, on the platinum complex binding conditions, and on the platinum content of the catalyst. Increasing the proportion of magnesium decreases the number of acid cites in the support and changes the properties of supported platinum. As a result, the n-decene formation selectivity under the appropriate conditions reaches 90% without a modifier added