23-Electron Octahedral Molybdenum Cluster Complex [{Mo6I8}Cl6]−
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Журнал |
Inorganic Chemistry
ISSN: 0020-1669
, E-ISSN: 1520-510X
|
| Вых. Данные |
Год: 2018,
Том: 57,
Номер: 2,
Страницы: 811-820
Страниц
: 10
DOI:
10.1021/acs.inorgchem.7b02760
|
| Ключевые слова |
CRYSTAL-STRUCTURE; HEXANUCLEAR MOLYBDENUM; ELECTRONIC-STRUCTURE; VIBRATIONAL-SPECTRA; SOLUTION CHEMISTRY; CHLORIDE CLUSTER; BASIS-SETS; BR; REDOX; Cl |
| Авторы |
Vorotnikova Natalya A.
1,2
,
Vorotnikov Yuri A.
1,2
,
Novozhilov Igor N.
1
,
Syrokvashin Mikhail M.
1
,
Nadolinny Vladimir A.
1
,
Kuratieva Natalia V.
1,3
,
Benoit David M.
4
,
Mironov Yuri V.
1,3
,
Walton Richard I.
5
,
Clarkson Guy J.
5
,
Kitamura Noboru
6
,
Sutherland Andrew J.
7
,
Shestopalov Michael A.
1,2,3
,
Efremova Olga A.
4
|
| Организации |
| 1 |
Nikolaev Institute of Inorganic Chemistry SB RAS
|
| 2 |
Scientific Institute of Clinical and Experimental Lymphology−branch of ICG SB RAS
|
| 3 |
Novosibirsk State University
|
| 4 |
School of Mathematics and Physical Sciences, University of Hull
|
| 5 |
Department of Chemistry, University of Warwick
|
| 6 |
Department of Chemistry, Faculty of Science, Hokkaido University
|
| 7 |
Aston Institute of Materials Research, Aston University
|
|
Photoactive transition metal compounds that are prone to reversible redox reactions are important for myriad applications, including catalysis, optoelectronics, and sensing. This article describes chemical and electrochemical methods to prepare cluster complex (Bu4N)[{Mo6I8}Cl6], a rare example of a 23 e– cluster complex within the family of octahedral clusters of Mo, W, and Re. The low temperature and room temperature crystal structures; electronic structure; and the magnetic, optical, and electrochemical properties of this complex are described.