Pseudomacrobicyclic Phthalocyaninate-Capped Cobalt(III) tris-Pyridineoximates: Template Synthesis, X-Ray Structure and Spectral Characteristics
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Журнал |
Macroheterocycles (Макрогетероциклы)
ISSN: 1998-9539
|
| Вых. Данные |
Год: 2019,
Том: 12,
Номер: 2,
Страницы: 193-197
Страниц
: 5
DOI:
10.6060/mhc190550d
|
| Ключевые слова |
Cobalt complexes; Hafnium complexes; Macrocyclic compounds; Phthalocyanines; Polynuclear complexes; Template reactions; Zirconium complexes |
| Авторы |
Belova Svetlana A.
1
,
Dudkin Semyon V.
1
,
Belov Alexander S.
1
,
Nelyubina Yulia V.
1,2
,
Novikov Valentin V.
1,3
,
Zubavichus Yan V.
4
,
Voloshin Yan Z.
1,2
|
| Организации |
| 1 |
A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, 119991, Russian Federation
|
| 2 |
N.S. Kurnakov Institute of General and Inorganic Chemistry of Russian Academy of Sciences, Moscow, 119991, Russian Federation
|
| 3 |
Moscow Institute of Physics and Technology, Dolgoprudny, 141701, Russian Federation
|
| 4 |
G.K. Boreskov Institute of Catalysis of the Siberian Branch of Russian Academy of Sciences, Novosibirsk, 630090, Russian Federation
|
|
Информация о финансировании (6)
|
1
|
Российский фонд фундаментальных исследований
|
17-03-00587 (АААА-А17-117041210400-5)
|
|
2
|
Министерство науки и высшего образования Российской Федерации
|
|
|
3
|
Российский фонд фундаментальных исследований
|
19-03-00357 (АААА-А19-119011490212-9)
|
|
4
|
Российский научный фонд
|
17-73-20369 (АААА-А17-117073110030-6)
|
|
5
|
Российский фонд фундаментальных исследований
|
18-29-23007 (АААА-А19-119042590091-3)
|
|
6
|
European Commission
|
778245 H2020-MSCA-RISE-2017 CLATHROPROBES
|
First pseudomacrobicyclic phthalocyaninate-capped cobalt(III) tris-pyridineoximates were obtained in moderate yields (40-49%) by the direct template condensation of 2-acetylpyridineoxime with zirconium(IV) and hafnium(IV) phthalocyaninates on the cobalt ion as a matrix. These complexes were thoroughly characterized using elemental analysis, MALDI-TOF mass-spectrometry, NMR and UV-Vis spectroscopies and by the single-crystal X-ray diffraction. Their electrochemical behaviour was studied byusing the cyclic and differential pulse voltammetries. © ISUCT Publishing.