Synthesis and Crystal Structure of trans-[Ru(NO)(NH3)4SO4]ClO4 and [Ru(NO)(NH3)4SO4][Ru(NO)(NH3)3Cl(SO4)]HSO4•H2O
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Переводная
|
| Журнал |
Journal of Structural Chemistry
ISSN: 0022-4766
, E-ISSN: 1573-8779
|
| Вых. Данные |
Год: 2016,
Том: 57,
Номер: 6,
Страницы: 1182-1187
Страниц
: 6
DOI:
10.1134/s0022476616060184
|
| Ключевые слова |
ammino complexes; chloro complexes; IR spectroscopy; nitroso complexes; ruthenium; single crystal X-ray diffraction analysis; sulfato complexes; synthesis |
| Авторы |
Makhinya A.N.
1,2
,
Il’in M.A.
1,2
,
Baidina I.A.
1
,
Korol’kov I.V.
1,2
|
| Организации |
| 1 |
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
|
| 2 |
Novosibirsk National Research State University
|
|
After the addition of the saturated NaClO4 solution to a solution of trans-[Ru(NO)(NH3)4SO4]HSO4•H2O, trans-[Ru(NO)(NH3)4SO4]ClO4 perchlorate salt (I) is obtained with the yield of ~80%. The heating of trans-[Ru(NO)(NH3)4(H2O)](HSO4)SO4 at a temperature of ~220 °C results in a complete removal of coordination water and a partial removal of ammonia molecules. Successive treatment of the thermolysis product with sulfuric and hydrochloric acids yields [Ru(NO)(NH3)4SO4][Ru(NO)(NH3)3Cl(SO4)]HSO4•H2O crystals (II). The single crystal X-ray diffraction method is used to determine the structure of the compounds obtained. For I: space group P21/c, a = 6.6949(9) Å, b = 13.7049(19) Å, c = 12.8641(17) Å, β = 101.028(4)°; for II: space group Р21/c, a = 14.1304(4) Å, b = 12.4908(3) Å,, c = 11.6264(3) Å, β = 94.1980(10)°