Preparation of Vitamin K3 in Mo–V–P Heteropoly Acid Solutions by Diene Synthesis
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Переводная
|
| Журнал |
Kinetics and Catalysis
ISSN: 0023-1584
, E-ISSN: 1608-3210
|
| Вых. Данные |
Год: 2020,
Том: 61,
Номер: 2,
Страницы: 276-282
Страниц
: 7
DOI:
10.1134/S0023158420010012
|
| Ключевые слова |
diene synthesis; heteropoly acids; hydroquinone; naphthoquinones; oxidation |
| Авторы |
Gogin L.L.
1
,
Zhizhina E.G.
1
|
| Организации |
| 1 |
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
|
|
Информация о финансировании (1)
|
1
|
Федеральное агентство научных организаций России
|
0303-2016-0008
|
The possibility of obtaining vitamin K3 (2-methyl-1,4-naphthoquinone, menadione) by diene synthesis from accessible substrates such as 2-methylphenol (o-cresol) and 2-methylaniline (o-toluidine) was shown. The bifunctional catalysts of these processes are the aqueous solutions of Mo–V–P heteropoly acids, which allow the oxidation and diene synthesis to be performed as a one-pot process. © 2020, Pleiades Publishing, Ltd.