Role of Texture and Acidity of SAPO-34 in Methanol to Olefins Conversion
Научная публикация
Общая информация |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Переводная
|
Журнал |
Petroleum Chemistry
ISSN: 0965-5441
, E-ISSN: 1531-8532
|
Вых. Данные |
Год: 2020,
Том: 60,
Номер: 4,
Страницы: 471-478
Страниц
: 8
DOI:
10.1134/s0965544120040167
|
Ключевые слова |
SAPO-34, silicoaluminophosphate, TEAOH, mesoporous materials, methanol to olefins, MTO |
Авторы |
Shamanaeva I.A.
1
,
Yu Zh.
2,3
,
Utemov A.V.
4
,
Wu W.
2
,
Sladkovskiy D.A.
4
,
Parkhomchuk E.V.
1,3
|
Организации |
1 |
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
|
2 |
Heilongjiang University, Harbin, China
|
3 |
Novosibirsk State University, Novosibirsk, 630090 Russia
|
4 |
St. Petersburg State Technological Institute (Technical University), St. Petersburg, 190013 Russia
|
|
Информация о финансировании (1)
1
|
Федеральное агентство научных организаций России
|
0303-2016-0010
|
The effect of the amount of the molecular template tetraethylammonium hydroxide (TEAOH) in the precursor mixture on the physicochemical properties of SAPO-34 crystals has been examined, and the catalysts obtained have been tested in methanol conversion to lower olefins (MTO). The analysis of the textural and acidic properties of SAPO-34, which determine the high catalytic performances of catalysts in MTO, has been carried out. An effective catalyst possesses a high acidity and a developed surface with a large specific mesopore volume.