Reaction Space Organization Effect on Propane Pyrolysis in the Presence of a Nickel-Copper Catalyst
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Переводная
|
| Журнал |
Kinetics and Catalysis
ISSN: 0023-1584
, E-ISSN: 1608-3210
|
| Вых. Данные |
Год: 2014,
Том: 55,
Номер: 1,
Страницы: 87-92
Страниц
: 6
DOI:
10.1134/S0023158414010108
|
| Авторы |
Shinkarev V.V.
1
,
Khanaev V.M.
1,2
,
Solovʹev E.A.
1
|
| Организации |
| 1 |
Novosibirsk State Technical University, Novosibirsk, 630073 Russia
|
| 2 |
Boreskov Institute of Catalysis, Russian Academy of Sciences, Novosibirsk, 630090 Russia
|
|
Информация о финансировании (1)
|
1
|
Министерство образования и науки Российской Федерации
|
П-814
|
Propane pyrolysis at atmospheric pressures and temperatures of 500–700°C in the presence of a bimetallic catalyst containing 50 wt % Ni, 40 wt % Cu, and a silicon dioxide textural promoter has been investigated. It has been established experimentally that the reactor geometry and the way the reactants are let in and out exert an effect on the catalytic pyrolysis. The overall process rate is mainly determined by the heterogeneous reaction occurring on the catalyst surface. The homogeneous constituent of the process has an effect on the propane conversion at the early stages of the reaction.