EXAFS Characterisation of Metal Bonding in Highly Luminescent, UV Stable, Water-Soluble and Biocompatible Lanthanide Complexes Научная публикация
Конференция |
16th International Conference on X-ray Absorption Fine Structure 23-28 авг. 2015 , Karlsruhe |
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Журнал |
Journal of Physics: Conference Series
ISSN: 1742-6588 , E-ISSN: 1742-6596 |
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Вых. Данные | Год: 2016, Том: 712, Номер статьи : 012137, Страниц : 5 DOI: 10.1088/1742-6596/712/1/012137 | ||||||||||
Ключевые слова | Atomic physics; Biocompatibility; Coordination reactions; Methanol; Rare earth elements; X ray absorption; X ray diffraction | ||||||||||
Авторы |
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Организации |
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Реферат:
The combination of X-ray diffraction with EXAFS was employed to assess the coordination environment of lanthanide complexes in solutions. This method is based on the assumption that the local structure of lanthanide complexes in solution combines elements of the crystal structure of the complex in the solid state (single- or polycrystalline) and the elements of the local structure of a lanthanide salt, completely dissociated in the solvent (usually chlorides). The success of this approach is demonstrated with the lanthanide (III) 2,3,4,5,6-pentafluorobenzoate complexes, where the local structure in aqueous and methanol solutions were estimated. Moreover, the dissociation degree of the complexes in aqueous and methanol solutions was evaluated.
Библиографическая ссылка:
Kalyakina A.
, Utochnikova V.
, Trigub A.
, Zubavichus Y.
, Kuzmina N.
, Bräse S.
EXAFS Characterisation of Metal Bonding in Highly Luminescent, UV Stable, Water-Soluble and Biocompatible Lanthanide Complexes
Journal of Physics: Conference Series. 2016. V.712. 012137 :1-5. DOI: 10.1088/1742-6596/712/1/012137 WOS Scopus РИНЦ
EXAFS Characterisation of Metal Bonding in Highly Luminescent, UV Stable, Water-Soluble and Biocompatible Lanthanide Complexes
Journal of Physics: Conference Series. 2016. V.712. 012137 :1-5. DOI: 10.1088/1742-6596/712/1/012137 WOS Scopus РИНЦ
Файлы:
Полный текст от издателя
Даты:
Поступила в редакцию: | 15 апр. 2016 г. |
Опубликована в печати: | 1 мая 2016 г. |
Опубликована online: | 2 июн. 2016 г. |
Идентификаторы БД:
Web of science | WOS:000383249000138 |
Scopus | 2-s2.0-84978715230 |
РИНЦ | 27075459 |
Chemical Abstracts | 2017:633821 |
Chemical Abstracts (print) | 167:535389 |
OpenAlex | W2415499096 |