Template Synthesis and X-Ray Structure of the First Cobalt(II) Glyoximate Clathrochelate with Terminal Formyl Groups
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Журнал |
Macroheterocycles (Макрогетероциклы)
ISSN: 1998-9539
|
| Вых. Данные |
Год: 2016,
Том: 9,
Номер: 4,
Страницы: 402-405
Страниц
: 4
DOI:
10.6060/mhc161174v
|
| Ключевые слова |
Macrocyclic compounds, clathrochelates, template condensation |
| Авторы |
Zelinskii Genrikh E.
1
,
Belov Alexander S.
1
,
Vologzhanina Anna V.
1
,
Novikov Valentin V.
1
,
Pavlov Alexander A.
1
,
Zubavichus Yan V.
2
,
Voloshin Yan Z.
1,3
|
| Организации |
| 1 |
Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
|
| 2 |
National Research Center ‘‘Kurchatov Institute’’
|
| 3 |
I.M. Gubkin Russian State University of Oil and Gas
|
|
Cobalt(II) tris-glyoximate clathrochelate CoGm3(B4-C6H4CHO)2 with terminal reactive formyl group was obtained in moderate yield using direct template cross-linking of three molecules of glyoxime with 4-formylphenylboronic acid on a cobalt(II) ion as a matrix. Its molecular structure has been determined using single-crystal X-ray diffraction experiment