Insights into the Borohydride Electrooxidation Reaction on Metallic Nickel from Operando FTIRS, on-line DEMS and DFT Научная публикация
Журнал |
Electrochimica Acta
ISSN: 0013-4686 , E-ISSN: 1873-3859 |
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Вых. Данные | Год: 2021, Том: 389, Номер статьи : 138721, Страниц : 13 DOI: 10.1016/j.electacta.2021.138721 | ||||||||||
Ключевые слова | Borohydride oxidation reaction; Polycrystalline nickel electrode; Fourier-transform infrared spectroscopy; Differential electrochemical mass spectrometry; Density functional theory calculations | ||||||||||
Авторы |
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Организации |
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Информация о финансировании (2)
1 | Российский научный фонд | 18-73-00143 |
2 | The French National Research Agency | MobiDiC ANR-16-CE05-0009-01 |
Реферат:
Direct Borohydride Fuel Cells (DBFCs) are considered as promising power sources for portable and mobile applications. Their advantages are high theoretical energy density, and high theoretical cell voltage. Metallic Ni has recently emerged as a promising electrode material for DBFCs. In this work we combine electrochemical, operando Fourier-transform infrared spectroscopy (FTIRS), and online differential electrochemical mass spectrometry (DEMS) measurements with density functional theory (DFT) calculations to advance the understanding of the borohydride oxidation reaction on Ni.
Библиографическая ссылка:
Oshchepkov A.G.
, Braesch G.
, Rostamikia G.
, Bonnefont A.
, Janik M.J.
, Chatenet M.
, Savinova E.R.
Insights into the Borohydride Electrooxidation Reaction on Metallic Nickel from Operando FTIRS, on-line DEMS and DFT
Electrochimica Acta. 2021. V.389. 138721 :1-13. DOI: 10.1016/j.electacta.2021.138721 WOS Scopus РИНЦ
Insights into the Borohydride Electrooxidation Reaction on Metallic Nickel from Operando FTIRS, on-line DEMS and DFT
Electrochimica Acta. 2021. V.389. 138721 :1-13. DOI: 10.1016/j.electacta.2021.138721 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 4 мар. 2021 г. |
Принята к публикации: | 29 мая 2021 г. |
Опубликована online: | 5 июн. 2021 г. |
Опубликована в печати: | 1 сент. 2021 г. |
Идентификаторы БД:
Web of science | WOS:000687283100010 |
Scopus | 2-s2.0-85108409510 |
РИНЦ | 46857187 |
Chemical Abstracts | 2021:1391478 |
OpenAlex | W3166046881 |