Metal-Organic Coordination Polymers Formed from γ-Cyclodextrin and Divalent Metal Ions
Научная публикация
| Общая информация |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Журнал |
European Journal of Inorganic Chemistry
ISSN: 1434-1948
, E-ISSN: 1099-0682
|
| Вых. Данные |
Год: 2019,
Том: 2019,
Номер: 39-40,
Страницы: 4321-4327
Страниц
: 7
DOI:
10.1002/ejic.201900398
|
| Ключевые слова |
Alkaline earth metals; Coordination polymers; Cyclodextrins; Metal-organic frameworks; Structure elucidation |
| Авторы |
Koshevoy Evgeny I.
1
,
Samsonenko Denis G.
1,2
,
Berezin Alexey S.
1,2
,
Fedin Vladimir P.
1,2
|
| Организации |
| 1 |
Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Lavrentiev Av., 630090, Novosibirsk, Russian Federation
|
| 2 |
Novosibirsk State University, 2 Pirogova Street, 630090, Novosibirsk, Russian Federation
|
|
The chemistry of metal-organic frameworks based on cyclodextrins and alkali metals has been extensively investigated in recent years, but coordination polymers with non-alkali metals have been rarely reported. Here, we describe the synthesis and X-ray crystallographic characterization of a series of coordination polymers, [Ba(H2O)3(γ-CD)]Cl2·6H2O (γ-CD-Ba1), [Ba(H2O)(γ-CD)]Cl2·8H2O (γ-CD-Ba2), [Sr(H2O)(γ-CD)](NO3)2·9H2O (γ-CD-Sr), [Ca(γ-CD)2]Cl2·2CH3OH·16H2O (γ-CD-Ca), and [Pb(H2O)(γ-CD)](NO3)2·11H2O (γ-CD-Pb), which were obtained by reacting γ-cyclodextrin with alkaline earth metal ions and Pb2+. The coordination polymers formed from γ-cyclodextrin and Ca2+ and Ba2+ are obtained for the first time. The only compound in the studied series, γ-CD-Ba1, has a 3D structure. The other compounds have layered structures. In the structure of γ-CD-Ca, the coordination and number of γ-cyclodextrin molecules connected to the Ca2+ are different from those determined for a series of isostructural 2D coordination polymers, namely, γ-CD-Ba2, γ-CD-Sr and γ-CD-Pb. The metal-organic coordination polymer γ-CD-Pb exhibits photoluminescence in the near UV-region (λmax = 345 nm).