Activation of Molecular Oxygen in Trifluoroacetic Acid
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Переводная
|
| Журнал |
Russian Journal of Physical Chemistry A
ISSN: 0036-0244
, E-ISSN: 1531-863X
|
| Вых. Данные |
Год: 2012,
Том: 86,
Номер: 5,
Страницы: 889-891
Страниц
: 3
DOI:
10.1134/S0036024412050342
|
| Ключевые слова |
Activation, Molecular oxygen, Quantum chemical calculation, Trifluoroacetic acid |
| Авторы |
Vishnetskaya M.V.
1
,
Ivanova M.S.
1
,
Solkan V.N.
2
,
Zhidomirov G.M.
2
,
Melʹnikov M.Ya.
3
|
| Организации |
| 1 |
Gubkin State University of Petroleum and Gas, Moscow, 119991 Russia
|
| 2 |
Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991 Russia
|
| 3 |
Department of Chemistry, Moscow State University, Moscow, 119991 Russia
|
|
The possibility of the formation of the H2O 2 +· cation-radical was determined according to the data from nonempirical calculations for liquid trifluoroacetic acid, which forms a hydroperoxide radical after deprotonation. A catalytic cycle was obtained in which CF3COOH serves as a catalyst in the oxidation of a substrate by dissolved molecular oxygen.