A Study of Microporous Aluminophosphates Obtained in the Presence of Symmetrical di-n-Alkylamines
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Переводная
|
| Журнал |
Russian Chemical Bulletin
ISSN: 1066-5285
, E-ISSN: 1573-9171
|
| Вых. Данные |
Год: 2012,
Том: 61,
Номер: 10,
Страницы: 1867-1876
Страниц
: 10
DOI:
10.1007/s11172-012-0260-x
|
| Ключевые слова |
ATO structural type, di-n-alkylamines, di-n-butylamine, di-n-hexylamine, di-n-pentylamine, di-n-propylamine, hydrothermal synthesis, microporous aluminophosphates |
| Авторы |
Kikhtyanin O.V.
1
,
Toktarev A.V.
1
,
Ayupov A.B.
1
,
Boldyreva N.N.
1
,
Echevskii G.V.
1
|
| Организации |
| 1 |
G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences,
5 prosp. Akad. Lavrent´eva, 630090 Novosibirsk, Russian Federation
|
|
Microporous aluminophosphates and silicoaluminophosphates were obtained by hydrothermal synthesis with a number of symmetrical di-n-alkylamines as templates. The influence of the reagents and chemical composition of the starting reaction gel on the phase composition of the products obtained was studied. Pure ATO-type crystals were formed when the organic component was abundant in the reaction mixture and aluminum isopropoxide served as an aluminum source. Various physicochemical investigations revealed that the properties of the products obtained depend on the amine nature.