Hydroxides of Transition Metals as Artificial Catalysts for Oxidation of Water to Dioxygen Обзор
Конференция |
Photochemical Conversion and Storage of Solar Energy: 12th International conference 09-14 авг. 1998 , Berlin |
||
---|---|---|---|
Журнал |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
||
Вых. Данные | Год: 2000, Том: 58, Номер: 2-3, Страницы: 71-88 Страниц : 8 DOI: 10.1016/S0920-5861(00)00243-1 | ||
Ключевые слова | Transition metals; Artificial catalysts; Dioxygen evolution; Photosystem II; Aqueous solutions; Hydroxides | ||
Авторы |
|
||
Организации |
|
Информация о финансировании (2)
1 | Российский фонд фундаментальных исследований | 98-03-32410 |
2 | Совет по грантам Президента Российской Федерации | 96-10-15-97586 |
Реферат:
Hydroxides of transition metals cations like Fe(III), Co(III), Mn(III), Ru(IV), etc., appear to be efficient artificial catalysts in oxidation of water to O2. The paper describes some catalytic properties of these hydroxides. The hydroxide-based catalysts for the water oxidation can be obtained in three modifications: bulky (individual and binary), supported on the ion exchange resins or conventional oxide supports (SiO2, TiO2, Al2O3, zeolites), and colloidal catalysts stabilized by starch. The possible mechanism of the catalytic reaction, including the stage of the formation of peroxocomplexes as intermediates is under discussion. Some similarities are drawn between the catalytic properties of hydroxide catalysts and those of the manganese-based oxygen evolving complex of the Photosystem II of green plants.
Библиографическая ссылка:
Elizarova G.L.
, Zhidomirov G.M.
, Parmon V.N.
Hydroxides of Transition Metals as Artificial Catalysts for Oxidation of Water to Dioxygen
Catalysis Today. 2000. V.58. N2-3. P.71-88. DOI: 10.1016/S0920-5861(00)00243-1 WOS Scopus РИНЦ
Hydroxides of Transition Metals as Artificial Catalysts for Oxidation of Water to Dioxygen
Catalysis Today. 2000. V.58. N2-3. P.71-88. DOI: 10.1016/S0920-5861(00)00243-1 WOS Scopus РИНЦ
Даты:
Опубликована online: | 18 апр. 2000 г. |
Опубликована в печати: | 12 мая 2000 г. |
Идентификаторы БД:
Web of science | WOS:000087198800003 |
Scopus | 2-s2.0-0033752126 |
РИНЦ | 13352114 |
Chemical Abstracts | 2000:258957 |
Chemical Abstracts (print) | 132:339799 |
OpenAlex | W2026951811 |