Effect of Oxalic Acid Content and Medium of Thermal Treatment on Physicochemical and Catalytic Properties of MoVTeNb Oxide Catalysts in Propane Ammoxidation Научная публикация
Журнал |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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Вых. Данные | Год: 2007, Том: 328, Номер: 2, Страницы: 195-200 Страниц : 6 DOI: 10.1016/j.apcata.2007.06.010 | ||||
Ключевые слова | Acrylonitrile, Ammoxidation, M1, M2, MoVTeNb mixed oxide, Phase structure, Propane | ||||
Авторы |
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Организации |
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Реферат:
Catalytic characteristics of MoV0.3Te0.23Nb0.12Ox catalysts in propane ammoxidation depend strongly on the quantity of oxalic acid present during slurry preparation and on the redox conditions during thermal treatment of the catalyst. Two stage thermal treatment (320 °C in air, 600 °C in He) and oxalate anion to niobium ratio in the slurry С2О42−/Nb = 3–5 have been shown to result in the catalysts with the best catalytic properties. Optimal catalysts have been found to contain M1 and M2 crystalline phases in the ratio of 3:1 or more. When the molar ratio С2О42−/Nb exceeds 3.5, tellurium is lost during calcination in He and other phases beside M1 and M2 are formed.
Библиографическая ссылка:
Popova G.Y.
, Andrushkevich T.V.
, Aleshina G.I.
, Plyasova L.M.
, Khramov (Khramov) M.I.
Effect of Oxalic Acid Content and Medium of Thermal Treatment on Physicochemical and Catalytic Properties of MoVTeNb Oxide Catalysts in Propane Ammoxidation
Applied Catalysis A: General. 2007. V.328. N2. P.195-200. DOI: 10.1016/j.apcata.2007.06.010 WOS Scopus РИНЦ
Effect of Oxalic Acid Content and Medium of Thermal Treatment on Physicochemical and Catalytic Properties of MoVTeNb Oxide Catalysts in Propane Ammoxidation
Applied Catalysis A: General. 2007. V.328. N2. P.195-200. DOI: 10.1016/j.apcata.2007.06.010 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 16 мар. 2007 г. |
Принята к публикации: | 11 июн. 2007 г. |
Опубликована online: | 17 июн. 2007 г. |
Опубликована в печати: | 10 сент. 2007 г. |
Идентификаторы БД:
Web of science | WOS:000249173300013 |
Scopus | 2-s2.0-34547119953 |
РИНЦ | 13557292 |
Chemical Abstracts | 2007:831626 |
Chemical Abstracts (print) | 147:387844 |
OpenAlex | W2079977378 |