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Design and Testing of Structured Catalysts for Internal Reforming of CH4 in Intermediate Temperature Solid Oxide Fuel Cells (IT SOFC) Научная публикация

Общее Язык: Английский, Жанр: Статья (Full article),
Статус опубликования: Опубликована, Оригинальность: Оригинальная
Конференция 12th International Symposium on Solid Oxide Fuel Cells
01-06 мая 2011 , Montreal
Журнал ECS Transactions
ISSN: 1938-5862 , E-ISSN: 1938-6737
Вых. Данные Год: 2011, Том: 35, Номер: 1, Страницы: 2771-2780 Страниц : 10 DOI: 10.1149/1.3570276
Ключевые слова METHANE; PERFORMANCE; ANODES
Авторы Smirnova A.L. 1 , Sadykov V.A. 2,3 , Mezentseva N.V. 2 , Bunina R.V. 2 , Pelipenko V.V. 2 , Alikina G.M. 2 , Krieger T.A. 2 , Bobrova L.N. 2 , Smorygo O. 4 , van Berkel F. 5 , Rietveld B. 5
Организации
1 Eastern Connecticut State University, Willimantic, CT, USA
2 Boreskov Institute of Catalysis, 630090 Novosibirsk, Russia
3 Novosibirsk State University, Novosibirsk, 630090, Russia
4 Powder Metallurgy Institute, Minsk, 220005, Belarus
5 Energy Research Center of the Netherlands, Petten, 1755LE, The Netherlands

Информация о финансировании (5)

1 European Commission 20089 FP6-2004-ENERGY-3 SOFC600
2 Президиум РАН 27
3 Президиум СО РАН 57
4 North Atlantic Treaty Organization SfP-980878
5 Российский фонд фундаментальных исследований 09-03-12317

Реферат: Procedures for the synthesis of nanocomposite anode materials comprised of Ni-YSZ promoted by doped Ce-Zr-O fluorite-like or La-Pr-Mn-Cr-O perovskite-like oxides and Pt/Ru were elaborated. Their composition, structure, reactivity, and catalytic properties in CH4 steam reforming were characterized using various techniques, such as SEM, TEM, EDX, TPR, and I-V testing in SOFC conditions. The optimized nanocomposites supported on compressed foam Ni-Al substrates demonstrated high and stable performance at H2O:CH4=1:2 ratio without coking or sintering. For the SOFC testing, the planar catalytic substrates with the surface area of 5x5 cm2 have been used. The demonstrated SOFC performance in the internal CH4 reforming mode was close to the performace obtained with the humidified hydrogen. The achieved power density was up to 300-800 mW/cm2 at 600-800 oC meeting the targets of the area specific resistance, fuel effficiency, and power density.
Библиографическая ссылка: Smirnova A.L. , Sadykov V.A. , Mezentseva N.V. , Bunina R.V. , Pelipenko V.V. , Alikina G.M. , Krieger T.A. , Bobrova L.N. , Smorygo O. , van Berkel F. , Rietveld B.
Design and Testing of Structured Catalysts for Internal Reforming of CH4 in Intermediate Temperature Solid Oxide Fuel Cells (IT SOFC)
ECS Transactions. 2011. V.35. N1. P.2771-2780. DOI: 10.1149/1.3570276 WOS Scopus РИНЦ
Даты:
Опубликована online: 16 дек. 2019 г.
Идентификаторы:
Web of science WOS:000300770105029
Scopus 2-s2.0-84856875640
РИНЦ 18035067
Chemical Abstracts 2011:902957
Chemical Abstracts (print) 156:207745
Альметрики: