Unique Shortening of Carbon Chain During Reduction of Aliphatic Nitro Compounds to Amines in the Presence of Supercritical Isopropanol on Alumina Научная публикация
Журнал |
The Journal of Supercritical Fluids
ISSN: 0896-8446 , E-ISSN: 1872-8162 |
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Вых. Данные | Год: 2015, Том: 103, Страницы: 101-104 Страниц : 4 DOI: 10.1016/j.supflu.2015.04.029 | ||||||
Ключевые слова | Aliphatic amine, Alumina, Hydrogen transfer, Nitro group, Reduction, Supercritical isopropanol | ||||||
Авторы |
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Организации |
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Информация о финансировании (1)
1 | Российский фонд фундаментальных исследований | 14-08-00210 |
Реферат:
Transformations of lower aliphatic nitrocompounds in supercritical isopropanol in a flow reactor in the presence of alumina were studied. In experiments with 1-nitropropane, the dominant process was the never-before-observed formation of an amine with a shorter by one carbon atom chain as compared to the initial nitroalkane. The reaction mechanism was suggested which adequately explained the formation of all detected products. The reactions of nitroethane and nitromethane partly proceeded by a new transformation route yielding isopropylamine
Библиографическая ссылка:
Sivcev V.P.
, Volcho K.P.
, Salakhutdinov N.F.
, Anikeev V.I.
Unique Shortening of Carbon Chain During Reduction of Aliphatic Nitro Compounds to Amines in the Presence of Supercritical Isopropanol on Alumina
The Journal of Supercritical Fluids. 2015. V.103. P.101-104. DOI: 10.1016/j.supflu.2015.04.029 WOS Scopus РИНЦ
Unique Shortening of Carbon Chain During Reduction of Aliphatic Nitro Compounds to Amines in the Presence of Supercritical Isopropanol on Alumina
The Journal of Supercritical Fluids. 2015. V.103. P.101-104. DOI: 10.1016/j.supflu.2015.04.029 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 21 янв. 2015 г. |
Принята к публикации: | 28 апр. 2015 г. |
Опубликована online: | 7 мая 2015 г. |
Опубликована в печати: | 1 авг. 2015 г. |
Идентификаторы БД:
Web of science | WOS:000356984100013 |
Scopus | 2-s2.0-84929629404 |
РИНЦ | 47506584 |
Chemical Abstracts | 2015:835442 |
Chemical Abstracts (print) | 163:161111 |
OpenAlex | W589617809 |