Study on Thermal Decomposition of Double Complex Salt [Pd (NH3) 4][PtCl6]
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Журнал |
Journal of Thermal Analysis and Calorimetry
ISSN: 1388-6150
, E-ISSN: 1572-8943
|
| Вых. Данные |
Год: 2016,
Том: 123,
Номер: 2,
Страницы: 1183-1195
Страниц
: 13
DOI:
10.1007/s10973-015-5002-5
|
| Ключевые слова |
PdPt alloy nanoparticles, Thermal analysis, Thermal decomposition, XPS, XRD, [Pd(NH3)4][PtCl6] |
| Авторы |
Asanova Tatyana
1
,
Asanov Igor
1,2
,
Zadesenets Andrey
1,2
,
Filatov Evgeniy
1,2
,
Plyusnin Pavel
1,2
,
Gerasimov Evgeniy
3
,
Korenev Sergey
1,2
|
| Организации |
| 1 |
Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk, Russia 630090
|
| 2 |
Novosibirsk State University, Novosibirsk, Russia 630090
|
| 3 |
Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia 630090
|
|
Информация о финансировании (2)
|
1
|
Российский фонд фундаментальных исследований
|
12-02-00354
|
|
2
|
Российский фонд фундаментальных исследований
|
14-03-00129
|
Thermal decomposition of double complex salt [Pd(NH3)4][PtCl6] in a helium atmosphere has been studied by ex situ X-ray diffraction, X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy. Statistical multivariate curve resolution approach to XPS and Auger spectra analysis was applied. This approach was compared with a convenient XPS analysis, demonstrating comparable results and its effectiveness in analysis of sample containing components with various oxidation states, but a little difference in composition. The result obtained allows the complex salt to use as a perspective single-source precursor in one-pot synthesis of PdPt alloy nanoparticles. To examine the precursor, thermal decomposition and shock of [Pd(NH3)4][PtCl6] were performed under various conditions in inert and reduction atmospheres and the final products were studied