Preparation of Zn-Modified Nano-ZSM-5 Zeolite and Its Catalytic Performance in Aromatization of 1-Hexene Научная публикация
Журнал |
Transactions of Nonferrous Metals Society of China
ISSN: 1003-6326 |
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Вых. Данные | Год: 2015, Том: 25, Номер: 5, Страницы: 1580-1586 Страниц : 7 DOI: 10.1016/S1003-6326(15)63761-X | ||||
Ключевые слова | aromatization, catalytic performance, isomorphous substitution, nano-ZSM-5 zeolite, Zn-modification | ||||
Авторы |
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Организации |
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Информация о финансировании (1)
1 | National Natural Science Foundation of China | 21276067 |
Реферат:
The promoting effect of introducing Zn into nano-ZSM-5 zeolites by conventional impregnation method and isomorphous substitution on the performance of 1-hexene aromatization was investigated. The nano-ZSM-5 zeolite was synthesized by a seed-induced method without organic templates. The Zn-modified nano-ZSM-5 zeolite catalysts, xZn/HNZ5 and yZn/Al–HNZ5, were prepared by the conventional impregnation method and isomorphous substitution, respectively. The structure, chemical composition and acidity of the catalysts were characterized by XRD, XRF, N2 adsorption, SEM, NH3-TPD and Py-IR, while the catalytic properties were evaluated at 480 °C and a weight hourly space velocity (WHSV) of 2.0 h–1 in the aromatization procedure of 1-hexene. Compared with xZn/HNZ5, yZn/Al–HNZ5 exhibited smaller particles and higher dispersion of Zn species, which led to greater intergranular mesopore and homogeneous acidity distribution. Experimental results indicated that the synergy effect between the Brønsted and Lewis acid sites of the isomorphously substituted nano-ZSM-5 zeolites could significantly increase aromatics yield and improve catalytic stability in the 1-hexene aromatization.
Библиографическая ссылка:
Wang G-l.
, Wu W.
, Zan W.
, Bai X-f.
, Wang W-j.
, QI X.
, Kikhtyanin O.V.
Preparation of Zn-Modified Nano-ZSM-5 Zeolite and Its Catalytic Performance in Aromatization of 1-Hexene
Transactions of Nonferrous Metals Society of China. 2015. V.25. N5. P.1580-1586. DOI: 10.1016/S1003-6326(15)63761-X WOS Scopus РИНЦ
Preparation of Zn-Modified Nano-ZSM-5 Zeolite and Its Catalytic Performance in Aromatization of 1-Hexene
Transactions of Nonferrous Metals Society of China. 2015. V.25. N5. P.1580-1586. DOI: 10.1016/S1003-6326(15)63761-X WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 8 янв. 2014 г. |
Принята к публикации: | 5 мар. 2014 г. |
Опубликована в печати: | 1 мая 2015 г. |
Опубликована online: | 12 июн. 2015 г. |
Идентификаторы БД:
Web of science | WOS:000356221500028 |
Scopus | 2-s2.0-84930975589 |
РИНЦ | 24049399 |
Chemical Abstracts | 2015:1257944 |
OpenAlex | W2213164071 |