Acid-Base Properties and Catalytic Activity of Metal-Organic Frameworks: A View from Spectroscopic and Semiempirical Methods
Обзор
| Общее |
Язык:
Английский,
Жанр:
Обзор (Review),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Журнал |
Catalysis Reviews: Science and Engineering
ISSN: 0161-4940
, E-ISSN: 1520-5703
|
| Вых. Данные |
Год: 2016,
Том: 58,
Номер: 2,
Страницы: 209-307
Страниц
: 99
DOI:
10.1080/01614940.2016.1128193
|
| Ключевые слова |
Acid-base properties, catalytic properties, metal-organic frameworks, spectroscopic methods, theoretical methods |
| Авторы |
Panchenko Valentina N.
1,2,3
,
Timofeeva Maria N.
1,2,3
,
Jhung Sung Hwa
4
|
| Организации |
| 1 |
Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
|
| 2 |
Novosibirsk State University, Novosibirsk, Russia
|
| 3 |
Novosibirsk State Technical University, Novosibirsk, Russia
|
| 4 |
Department of Chemistry and Green-Nano Materials Research Center, Kyungpook National University, Daegu, Republic of Korea
|
|
Информация о финансировании (3)
|
1
|
Федеральное агентство научных организаций России
|
V.44.2.12.
|
|
2
|
Министерство образования и науки Российской Федерации
|
|
|
3
|
National Research Foundation of Korea
|
2013R1A2A2A01007176
|
This article summarizes several approaches for understanding the catalytic chemistry and “structure-surface acidity-reactivity” relationships in a multiplicity of catalytic applications of a continually increasing assemblage of metal-organic frameworks (MOFs) structures. The various spectroscopic techniques for acid-base characterization of MOFs are reviewed. The experimental requirements and the type and nature of probe molecules available are also discussed. Special emphasis is given to the revealing of the surface acid-base effect on the catalytic performance of MOFs.