Development of Active Catalysts for Low Pt Loading Cathodes of PEMFC by Surface Tailoring of Nanocarbon Materials
Научная публикация
| Общее |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Конференция |
1st International Symposium on Carbon for Catalysis
18-20 июл. 2004
,
Lausanne
|
| Журнал |
Catalysis Today
ISSN: 0920-5861
, E-ISSN: 1873-4308
|
| Вых. Данные |
Год: 2005,
Том: 102-103,
Страницы: 58-66
Страниц
: 9
DOI:
10.1016/j.cattod.2005.02.007
|
| Ключевые слова |
Carbon nanofiber, Catalyst, Cathode, CNF, Low loading, Nanocarbon, PEMFC, Platinum, Supermicroporous carbon |
| Авторы |
Ismagilov Z.R.
1
,
Kerzhentsev M.A.
1
,
Shikina N.V.
1
,
Lisitsyn A.S.
1
,
Okhlopkova L.B.
1
,
Barnakov Ch.N.
2
,
Sakashita Masao
3
,
Iijima Takashi
4
,
Tadokoro Kenichiro
4
|
| Организации |
| 1 |
Boreskov Institute of Catalysis, Prospekt Akademika Lavrentieva 5, Novosibirsk 630090, Russia
|
| 2 |
Institute of Coal and Coal Chemistry, Kemerovo 650616, Russia
|
| 3 |
JATIS, Sogo-kojimachi No. 3 Building, 1-6 Kojimachi, Chiyoda-ku, Tokyo 102-0086, Japan
|
| 4 |
Nippon Steel Corporation, 20-1 Shintomi, Futtsu, Chiba 293-8511, Japan
|
|
Информация о финансировании (2)
|
1
|
Nederlandse Organisatie voor Wetenschappelijk Onderzoek
|
|
|
2
|
New Energy and Industrial Technology Development Organization
|
|
The use of novel nanocarbon supports—carbon nanofibers (CNF) and amorphous supermicroporous carbons (ASC) for synthesis of platinum cathode catalysts for proton exchange membrane fuel cells (PEMFC) was investigated. Different types of CNF—with “parallel” and “deck of cards” arrangement of graphitic planes and samples of ASC originating from different organic precursors were synthesized and characterized by XRD, electron microscopy and adsorption methods. Platinum catalysts for PEMFC cathodes on different structural types of CNF and one sample of ASC were synthesized and characterized by XRD, electron microscopy, CO adsorption and by studying characteristics of conventional membrane electrode assembly (MEA) cell with a low Pt loading level of 0.02–0.09 mg/cm2. The MEA testing showed that the Pt cathode catalysts on CNF exhibit inferior performance in comparison with a catalyst on conventional carbon black support Pt/Vulcan XC-72R. The cathode catalyst prepared on ASC support exhibits considerably better output in MEA, compared with Pt/Vulcan XC-72R even at a lower Pt loading.