Quantitative Studies on the Heterogeneous Gas-Phase Photooxidation of CO and Simple VOCs by Air over TiO2 Научная публикация
Журнал |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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Вых. Данные | Год: 1997, Том: 39, Номер: 3, Страницы: 207-218 Страниц : 12 DOI: 10.1016/S0920-5861(97)00102-8 | ||||
Ключевые слова | PHOTOCATALYTIC OXIDATION; TITANIUM-DIOXIDE; TRICHLOROETHYLENE; ACETONE; FORMALDEHYDE; ACETALDEHYDE; DEGRADATION; TOLUENE; ETHANOL | ||||
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Реферат:
This paper presents a collection of the authors' recent results concerning the photocatalytic oxidation of gaseous organics and CO over TiO2 in different kinds of reactors with the accent on providing quantitative information about the photoprocesses studied to enable comparison with results of other authors. A static reactor, an annular flow reactor and a flow-circulating reactor were used. Oxidation of acetone, ethanol and diethyl ether in the static reactor ultimately leads to CO2, with acetaldehyde, acetaldehyde and ethyl acetate being the intermediate products in the oxidation of ethanol and diethyl ether, respectively. Acetone is completely oxidized to CO2 during a single pass through the annular flow reactor if the residence time is greater than 1 min. Temperature dependence of the acetone photooxidation rate in the flow-circulating reactor has a maximum at 80°C. Four specimens of TiO2 prepared by principally different methods were tested in oxidation of acetone and CO in the flow-circulating reactor. It has been found that photoplatinization retards the acetone oxidation and prohibits considerably the CO oxidation. These results indicate that the process of heterogeneous photocatalytic oxidation can be substantially improved by optimization of both the catalyst and the conditions of the photocatalytic process.
Библиографическая ссылка:
Vorontsov A.V.
, Savinov E.N.
, Barannik G.B.
, Troitsky V.N.
, Parmon V.N.
Quantitative Studies on the Heterogeneous Gas-Phase Photooxidation of CO and Simple VOCs by Air over TiO2
Catalysis Today. 1997. V.39. N3. P.207-218. DOI: 10.1016/S0920-5861(97)00102-8 WOS Scopus РИНЦ
Quantitative Studies on the Heterogeneous Gas-Phase Photooxidation of CO and Simple VOCs by Air over TiO2
Catalysis Today. 1997. V.39. N3. P.207-218. DOI: 10.1016/S0920-5861(97)00102-8 WOS Scopus РИНЦ
Даты:
Опубликована в печати: | 29 нояб. 1997 г. |
Опубликована online: | 20 апр. 1998 г. |
Идентификаторы БД:
Web of science | WOS:000071217000008 |
Scopus | 2-s2.0-0002795642 |
РИНЦ | 13263762 |
Chemical Abstracts | 1997:753589 |
Chemical Abstracts (print) | 128:134245 |
OpenAlex | W1968380995 |