Carbonization and Regeneration of Mo/ZSM-5 Catalysts for Methane Dehydroaromatization
Научная публикация
| Общая информация |
Язык:
Английский,
Жанр:
Статья (Full article),
Статус опубликования:
Опубликована,
Оригинальность:
Оригинальная
|
| Журнал |
Eurasian Chemico-Technological Journal
ISSN: 1562-3920
|
| Вых. Данные |
Год: 2005,
Том: 7,
Номер: 2,
Страницы: 115-121
Страниц
: 7
DOI:
10.18321/ectj622
|
| Ключевые слова |
CARBONIZATION, REGENERATION, MO/ZSM-5 CATALYSTS, METHANE, DEHYDROAROMATIZATION |
| Авторы |
Ismagilov Z.R.
,
Tsikoza L.T.
,
Matus E.V.
,
Litvak G.S.
,
Ismagilov I.Z.
,
Sukhova O.B.
|
| Организации |
| 1 |
Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva, 5, 630090 Novosibirsk, Russia
|
|
The character of carbonaceous deposits formed during methane dehydroaromatization reaction in the presence of Mo/ZSM-5 catalysts was studied s by differential thermal analysis. The dependence of the concentration and condensation degree (C/H ratio) of the carbonaceous deposits on the catalyst synthesis conditions (Mo content = 1-10%, Si/Al ratio in the initial H-ZSM-5 = 17-45) and reaction conditions (feed flow rate = 405-1620 h-1, methane concentration = 90-98%, reaction temperature = 720-780°C) was investigated. The oxidative treatment conditions of carbonized Mo/ZSM-5 catalysts providing stable operation of the catalysts under multiple reaction-oxidative treatment cycles were selected.