First Examples of Chalcofluoride Rhenium Cluster Complexes with Cubane-Like Anions [Re4Q4F12]4– (Q = S, Se) Научная публикация
Журнал |
European Journal of Inorganic Chemistry
ISSN: 1434-1948 , E-ISSN: 1099-0682 |
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Вых. Данные | Год: 2005, Номер: 12, Страницы: 2476-2479 Страниц : 4 DOI: 10.1002/ejic.200500130 | ||||||||
Ключевые слова | Chalcofluoride complexes, Density functional calculations, Tetrahedral rhenium cluster | ||||||||
Авторы |
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Организации |
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Реферат:
Two rhenium tetrahedral cluster chalcofluoride compounds, K4[Re4S4F12]·3.4 H2O (1) and K4[Re4Se4F12]·6 H2O (2), have been synthesized for the first time by a reaction of Re4Q4(TeCl2)4Cl8 (Q = S, Se) with molten KHF2. Both compounds have been characterized by single-crystal X-ray diffraction methods. Compound 1 crystallizes in the trigonal space group Requation image with 24 formula units per cell [a = b = 23.6503(3) Å, c = 25.2697(7) Å,
V = 12240.6(4) Å3 (T = 293 K)]; compound 2 crystallizes in the monoclinic space group Pequation image with four formula units per cell [a = 10.6451(3) Å, b = 14.6853(4) Å, c = 16.9349(5) Å, α = 66.8420(10)°, β = 84.8460(10)°, γ = 85.5740(10)°, V = 2421.69(12) Å3 (T = 293 K)]. Hydrophilic terminal fluoride ligands of cluster anions are included in the hydrogen bond systems of their hydrate shells.
Библиографическая ссылка:
Mironov Y.V.
, Yarovoi S.S.
, Naumov D.Y.
, Kuratieva N.V.
, Kozlova S.G.
, Simon A.
, Fedorov V.E.
First Examples of Chalcofluoride Rhenium Cluster Complexes with Cubane-Like Anions [Re4Q4F12]4– (Q = S, Se)
European Journal of Inorganic Chemistry. 2005. N12. P.2476-2479. DOI: 10.1002/ejic.200500130 WOS Scopus РИНЦ
First Examples of Chalcofluoride Rhenium Cluster Complexes with Cubane-Like Anions [Re4Q4F12]4– (Q = S, Se)
European Journal of Inorganic Chemistry. 2005. N12. P.2476-2479. DOI: 10.1002/ejic.200500130 WOS Scopus РИНЦ
Даты:
Поступила в редакцию: | 12 февр. 2005 г. |
Опубликована в печати: | 1 июн. 2005 г. |
Опубликована online: | 15 июн. 2005 г. |
Идентификаторы БД:
Web of science | WOS:000230068200024 |
Scopus | 2-s2.0-21244453931 |
РИНЦ | 13493659 |
Chemical Abstracts | 2005:591090 |
Chemical Abstracts (print) | 144:44518 |
OpenAlex | W2951319620 |