ESR Detection of Copper Ion Clusters in the Cu-Zn-Al Oxide Catalysts for Methanol Synthesis Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 1999, Volume: 40, Number: 1, Pages: 117-120 Pages count : 4 | ||||||
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Abstract:
It was found by ESR spectroscopy that the treatment of the Cu-Zn-Al oxide catalysts for methanol synthesis with pyridine did not produce isolated pyridinate complexes. In this case, three types of copper clusters were formed; two of them were assigned to the ordered Jahn-Teller clusters. It was suggested that the cluster structures consist of the Cu2+-O-M-O-Cu2+ oxide fragments (where IM is the Al3+, Zn2+, and Cu2+ ion), which were not decomposed upon treatment with pyridine.
Cite:
Altynnikov A.A.
, Anufrienko V.F.
, Rozovskii A.Y.
, Lin G.I.
, Lunina E.V.
, Sadykov V.A.
ESR Detection of Copper Ion Clusters in the Cu-Zn-Al Oxide Catalysts for Methanol Synthesis
Kinetics and Catalysis. 1999. V.40. N1. P.117-120. WOS Scopus РИНЦ
ESR Detection of Copper Ion Clusters in the Cu-Zn-Al Oxide Catalysts for Methanol Synthesis
Kinetics and Catalysis. 1999. V.40. N1. P.117-120. WOS Scopus РИНЦ
Original:
Алтынников А.А.
, Ануфриенко В.Ф.
, Розовский А.Я.
, Лин Г.И.
, Лунина Е.В.
, Садыков В.А.
Обнаружение кластеров ионов меди в оксидных Cu-Zn-Al-катализаторах синтеза метанола по данным ЭПР
Кинетика и катализ. 1999. Т.40. №1. С.129-133. РИНЦ
Обнаружение кластеров ионов меди в оксидных Cu-Zn-Al-катализаторах синтеза метанола по данным ЭПР
Кинетика и катализ. 1999. Т.40. №1. С.129-133. РИНЦ
Dates:
Submitted: | Dec 30, 1997 |
Identifiers:
Web of science | WOS:000078894900018 |
Scopus | 2-s2.0-0041491404 |
Elibrary | 13307293 |
Chemical Abstracts | 1999:176448 |
Chemical Abstracts (print) | 130:298288 |