Catalytic Hydrodechlorination of Polychlorinated Aromatic Hydrocarbons Full article
Conference |
18th Symposium on Halogenated Environmental Organic Pollutants 17-21 Aug 1998 , Stockholm |
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Journal |
Organohalogen Compounds
ISSN: 1026-4892 |
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Output data | Year: 1997, Volume: 31, Pages: 330-335 Pages count : 6 | ||
Authors |
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Affiliations |
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Abstract:
Liq.-phase hydrodechlorination of PhCl, C6Cl6, and polychlorinated biphenyls with H2 on Pd/C, Ni/C, or Pd-Ni/C was studied at 20-70° and 1-50 atm. The catalysts were prepd. via support impregnation with metal salt soln., drying, thermal treatment, and subsequent treatment with NaBH4 as reducing agent. Pd/C and Pd-Ni/C showed the highest activity and dechlorinated efficiently polychlorinated arenes at 70°. Kinetic studies proved the hydrodechlorination of these compds. to be consecutive reactions.
Cite:
Simagina V.I.
, Yakovlev V.A.
, Stoyanova I.V.
, Likholobov V.A.
Catalytic Hydrodechlorination of Polychlorinated Aromatic Hydrocarbons
Organohalogen Compounds. 1997. V.31. P.330-335. РИНЦ
Catalytic Hydrodechlorination of Polychlorinated Aromatic Hydrocarbons
Organohalogen Compounds. 1997. V.31. P.330-335. РИНЦ
Identifiers:
Elibrary | 28934248 |
Chemical Abstracts | 1998:199838 |
Chemical Abstracts (print) | 128:217139 |
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