Palladium(II), Copper(II), Iron(III), and Vanadium(V) Complexes with Heteropolyanion PW9 O9–34: 31P, 183W, 51V NMR and IR Spectroscopy Studies Full article
Journal |
Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318 |
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Output data | Year: 2001, Volume: 27, Number: 12, Pages: 838-845 Pages count : 8 DOI: 10.1023/A:1013056927629 | ||
Tags | Iron; Copper; Spectroscopy; Physical Chemistry; Aqueous Solution | ||
Authors |
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Affiliations |
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Funding (1)
1 | Russian Foundation for Basic Research | 00-15-97447 |
Abstract:
The formation of Pd(II)-containing and mixed Pd(II),Cu(II), Pd(II),Fe(III), and Pd(II),V(V) complexes with heteropolyanion PW9O9–34was studied using 31P, 183W, 51V NMR, visible UV and IR spectroscopy, and the differentiating dissolution methods. In an aqueous solution and at optimal pH (3.7), the monometallic complexes [Pd3(PW9O34)2]12–and [Pd3(PW9O34)2PdnOxHy]q–(nav= 3), the bimetallic complexes [Pd2Cu(PW9O34)2]12–, [Pd2Fe(PW9O34)2]11–, and [PdFe2(PW9O34)2]10–, and a mixture of the [Pd3(PW9O34)2PdnOxHy]q–(nav≈ 10) + [(VO)3(PW9O34)2]9–complexes are formed. The title complexes were isolated from solution as Cs+solid salts belonging to the same [M3(PW9O34)2] structural type.
Cite:
Detusheva L.G.
, Kuznetsova L.I.
, Fedotov M.A.
, Likholobov V.A.
, Dovlitova L.S.
, Vlasov A.A.
, Malakhov V.V.
Palladium(II), Copper(II), Iron(III), and Vanadium(V) Complexes with Heteropolyanion PW9 O9–34: 31P, 183W, 51V NMR and IR Spectroscopy Studies
Russian Journal of Coordination Chemistry. 2001. V.27. N12. P.838-845. DOI: 10.1023/A:1013056927629 WOS Scopus РИНЦ
Palladium(II), Copper(II), Iron(III), and Vanadium(V) Complexes with Heteropolyanion PW9 O9–34: 31P, 183W, 51V NMR and IR Spectroscopy Studies
Russian Journal of Coordination Chemistry. 2001. V.27. N12. P.838-845. DOI: 10.1023/A:1013056927629 WOS Scopus РИНЦ
Original:
Детушева Л.Г.
, Кузнецова Л.И.
, Федотов М.А.
, Лихолобов В.А.
, Довлитова Л.С.
, Власов А.А.
, Малахов В.В.
Комплексообразование палладия(II), меди(II), железа(III), ванадия(V) с гетерополианионом PW9O349- по данным ЯМР 31P, 183W, 51V и ИК-спектроскопии
Координационная химия. 2001. Т.27. №12. С.890-897. Scopus РИНЦ
Комплексообразование палладия(II), меди(II), железа(III), ванадия(V) с гетерополианионом PW9O349- по данным ЯМР 31P, 183W, 51V и ИК-спектроскопии
Координационная химия. 2001. Т.27. №12. С.890-897. Scopus РИНЦ
Dates:
Submitted: | Dec 25, 2000 |
Published print: | Dec 1, 2001 |
Identifiers:
Web of science | WOS:000172985600003 |
Scopus | 2-s2.0-24944567923 |
Elibrary | 13375181 |
Chemical Abstracts | 2002:30697 |
Chemical Abstracts (print) | 136:256270 |
OpenAlex | W220089399 |