An Ion Cyclotron Resonance Study of Reactions Between Molybdenum Oxide Ionic Clusters and Ammonia Full article
Journal |
Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X |
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Output data | Year: 2002, Volume: 76, Number: 9, Pages: 1454-1460 Pages count : 7 | ||
Tags | ammonia; molybdenum; nitrogen | ||
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Abstract:
Reactions between molybdenum oxygen-containing clusters MoxOy+ (x = 1-3, y = 1-9) and ammonia were studied by ion cyclotron resonance. The formation of several nitrogen-containing ions including the Mo3O7N2 complex with molecular nitrogen was observed. The upper and lower limits of bond energies in the complexes were estimated (kcal/mol): Mo+-NH (<92), MoO+-NH (<117), MoO2+-NH (<71), Mo2O5+-NH3 (>56), Mo3O8+-NH3 (>58), Mo3O8+-NH (>44), Mo3O7(NH3)(+)-NH3 (>58), Mo3O7+-2NH (>88), Mo3O7+-N-2 (>112) in the Mo=N-N=Mo structure, and Mo3O7+-N-2 (>56) in the Mo-N=N-Mo structure.
Cite:
Goncharov V.B.
, Fialko E.F.
An Ion Cyclotron Resonance Study of Reactions Between Molybdenum Oxide Ionic Clusters and Ammonia
Russian Journal of Physical Chemistry A. 2002. V.76. N9. P.1454-1460. WOS Scopus РИНЦ
An Ion Cyclotron Resonance Study of Reactions Between Molybdenum Oxide Ionic Clusters and Ammonia
Russian Journal of Physical Chemistry A. 2002. V.76. N9. P.1454-1460. WOS Scopus РИНЦ
Original:
Гончаров В.Б.
, Фиалко Е.Ф.
Ионный циклотронный резонанс в реакциях ионных кластеров оксида молибдена с аммиаком
Журнал физической химии. 2002. Т.76. №9. С.1610-1617. Scopus РИНЦ
Ионный циклотронный резонанс в реакциях ионных кластеров оксида молибдена с аммиаком
Журнал физической химии. 2002. Т.76. №9. С.1610-1617. Scopus РИНЦ
Dates:
Submitted: | Sep 4, 2001 |
Published print: | Sep 1, 2002 |
Identifiers:
Web of science | WOS:000178407400012 |
Scopus | 2-s2.0-0036710657 |
Elibrary | 13406939 |