Oxidation of Two-Electron 8-Tungsto-4-Vanadophosphate Heteropoly Blue by Molecular Oxygen in the Presence of Vanadyl Ions Full article
Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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Output data | Year: 1983, Volume: 32, Number: 4, Pages: 660-665 Pages count : 6 DOI: 10.1007/BF00953452 | ||
Tags | Oxidation; Oxygen; Acetic; Acetic Acid; Vanadium | ||
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Abstract:
Conclusions
1. The reduced 8-tungsto-4-vanadophosphate heteropoly acid (HPAc) hardly dissociates at all with the release of free vanadyl ions in 50% acetic acid at pH ≥ 3.
2. The kinetics of the oxidation of the heteropoly blue containing two vanadium(IV) atoms HxPW8V2 IV 40 −(9−x) were investigated by catalytic oxidation of vanadyl in the presence of the HPB. Rapid realization of the reaction requires further second-sphere addition of two or one vanadyl ion to the heteropoly anion.
Cite:
Kuznetsova L.I.
, Maksimovskaya R.I.
, Matveev K.I.
Oxidation of Two-Electron 8-Tungsto-4-Vanadophosphate Heteropoly Blue by Molecular Oxygen in the Presence of Vanadyl Ions
Russian Chemical Bulletin. 1983. V.32. N4. P.660-665. DOI: 10.1007/BF00953452 WOS Scopus РИНЦ
Oxidation of Two-Electron 8-Tungsto-4-Vanadophosphate Heteropoly Blue by Molecular Oxygen in the Presence of Vanadyl Ions
Russian Chemical Bulletin. 1983. V.32. N4. P.660-665. DOI: 10.1007/BF00953452 WOS Scopus РИНЦ
Original:
Кузнецова Л.И.
, Максимовская Р.И.
, Матвеев К.И.
Окисление молекулярным кислородом двухэлектронной 8-вольфрам-4-ванадофосфорной гетерополисини в присутствии ионов ванадила
Известия Академии наук. Серия химическая. 1983. №4. С.726-732. РИНЦ
Окисление молекулярным кислородом двухэлектронной 8-вольфрам-4-ванадофосфорной гетерополисини в присутствии ионов ванадила
Известия Академии наук. Серия химическая. 1983. №4. С.726-732. РИНЦ
Dates:
Submitted: | Jul 2, 1982 |
Published print: | Apr 1, 1983 |
Identifiers:
Web of science | WOS:A1983RT15800005 |
Scopus | 2-s2.0-34250144720 |
Elibrary | 30845592 |
OpenAlex | W2010849924 |
Citing:
DB | Citing |
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Web of science | 0 |