Preparation and Characterization of Magnesium Oxide-Bound Trichlorobis(tetrahydrofuran)titanium(III) Full article
Journal |
Chemical Papers
ISSN: 0366-6352 , E-ISSN: 1336-9075 |
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Output data | Year: 1981, Volume: 35, Number: 5, Pages: 613-619 Pages count : 7 | ||||
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Abstract:
The anchoring of the coordinatively unsaturated complex TiQ3(C4H80)2 to the surface of magnesium oxide leads to the formation of surface attached Ti(III) complexes, which were investigated by e.s.r. and i.r. spectroscopy. It has
been found that the anchoring of the original complex to the surface is achieved by the reaction of the complex with the basic centres on the surface of magnesium oxide. On thermal decomposition of thus formed surface complexes their aggregation takes place. By their reaction with oxygen the radical O2- arises which is coordinated to Ti(IV)
Cite:
Plesch G.
, Paukshtis E.A.
, Sanko E.S.
, Rapiova S.
, Yurchenko E.N.
, Zikmund M.
Preparation and Characterization of Magnesium Oxide-Bound Trichlorobis(tetrahydrofuran)titanium(III)
Chemical Papers. 1981. V.35. N5. P.613-619. WOS РИНЦ
Preparation and Characterization of Magnesium Oxide-Bound Trichlorobis(tetrahydrofuran)titanium(III)
Chemical Papers. 1981. V.35. N5. P.613-619. WOS РИНЦ
Dates:
Submitted: | Sep 12, 1980 |
Identifiers:
Web of science | WOS:A1981MT63100004 |
Elibrary | 47325760 |
Chemical Abstracts | 1982:45287 |
Chemical Abstracts (print) | 96:45287 |
Citing:
DB | Citing |
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Web of science | 4 |