Catalytic Oxidation of Carbon Monoxide in the Presence of Pd(II) and Heteropolyacids in an Alcohol Medium ArticleGenre_short.LETTER
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 1984, Volume: 25, Number: 5, Pages: 1089-1090 Pages count : 2 | ||
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Abstract:
The dependence of the composition of the products of CO oxidation on the reaction conditions was studied in the presence of PdCl2 or PdSO4, Na5H2PMo8V4O40 (I), MeOH or EtOH, and a min. amt. of H2O. At [H2O] = 0.5-1 mol L-1 the CO2 yield is the same for PdCl2 and PdSO4 and does not change with change in H+ concentration in MeOH or EtOH. With an increase in H2O concentration the CO2 yield increased sharply. In the presence of MeOH, Me2CO3 is also formed whereas in EtOH, Et2CO3 and EtO2CCO2Et are formed. The oxidation of CO occurred through the coordination to Pd with the participation of the alcohol. Oxidation of CO is accompanied by reduction of I, the reduced form of which is oxidized by O.
Cite:
Kuznetsova L.I.
, Matveev K.I.
Catalytic Oxidation of Carbon Monoxide in the Presence of Pd(II) and Heteropolyacids in an Alcohol Medium
Kinetics and Catalysis. 1984. V.25. N5. P.1089-1090. WOS РИНЦ
Catalytic Oxidation of Carbon Monoxide in the Presence of Pd(II) and Heteropolyacids in an Alcohol Medium
Kinetics and Catalysis. 1984. V.25. N5. P.1089-1090. WOS РИНЦ
Original:
Кузнецова Л.И.
, Матвеев К.И.
Каталитическое окисление окиси углерода в присутствии Pd(II) и гетерополикислоты в среде спиртов
Кинетика и катализ. 1984. Т.25. №5. С.1274-1275. РИНЦ
Каталитическое окисление окиси углерода в присутствии Pd(II) и гетерополикислоты в среде спиртов
Кинетика и катализ. 1984. Т.25. №5. С.1274-1275. РИНЦ
Dates:
Submitted: | Apr 9, 1984 |
Published print: | Sep 1, 1984 |
Identifiers:
Web of science | WOS:A1984AJR8700025 |
Elibrary | 30602848 |