Influence of the Nature of the Oxidizing-Agents on the Mechanism of the Oxidation of Carbon-Monoxide in the Presence of an Aqua Complex of Palladium(II) Full article
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Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 1985, Volume: 26, Number: 2, Pages: 404-408 Pages count : 5 | ||
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Abstract:
The kinetics of CO oxidation was studied in the presence of aquo complexes of Pd(II), VO2+, Fe3+, and heteropoly-acids H3PMO12O40, H4PMo11VO40, and H4PW11VO40. A comparison of the present and published results on oxidation with strong oxidizing agents, such as Cr2O72-, of Ce4+, reveals that for a fast oxidation, the oxidation potential should be 0.7-1.0 V. The intermediate carbonyl complexes of partially reduced Pd are the most active catalysts of the oxidation.
Cite:
Zhizhina E.G.
, Matveev K.I.
, Kuznetsova L.I.
Influence of the Nature of the Oxidizing-Agents on the Mechanism of the Oxidation of Carbon-Monoxide in the Presence of an Aqua Complex of Palladium(II)
Kinetics and Catalysis. 1985. V.26. N2. P.404-408. WOS РИНЦ
Influence of the Nature of the Oxidizing-Agents on the Mechanism of the Oxidation of Carbon-Monoxide in the Presence of an Aqua Complex of Palladium(II)
Kinetics and Catalysis. 1985. V.26. N2. P.404-408. WOS РИНЦ
Original:
Жижина Е.Г.
, Матвеев К.И.
, Кузнецова Л.И.
Влияние природы окислителей на механизм процесса окисления оксида углерода в присутствии аквакомплекса палладия (II)
Кинетика и катализ. 1985. Т.26. №2. С.461-465. РИНЦ
Влияние природы окислителей на механизм процесса окисления оксида углерода в присутствии аквакомплекса палладия (II)
Кинетика и катализ. 1985. Т.26. №2. С.461-465. РИНЦ
Dates:
Submitted: | Oct 13, 1983 |
Published print: | Mar 1, 1985 |
Identifiers:
Web of science | WOS:A1985AUZ1800017 |
Elibrary | 30603111 |
Citing:
DB | Citing |
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Web of science | 2 |