IR Spectroscopic Study of Hydrocarbon Adsorption on Oxide Catalysts. XVI. Interaction of C3H6 and C2H4 with V2O5/Al2O3 Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 1990, Volume: 31, Number: 3 pt 2, Pages: 571-577 Pages count : 7 | ||
Tags | Hydrocarbons - Adsorption; Olefins - Catalysis; Spectroscopy, Infrared | ||
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Abstract:
It has been shown that, on oxidized V2O5/Al2O3, olefins form alkoxides; in the case of C3H6, the alkoxides are converted to acetone, which gives enolate-like compounds at elevated temperatures. On the reduced catalyst, which contains V4+ and V3+ ions, C3H6 forms pi-complexes; at elevated temperatures and in the presence of O2, these complexes are converted to converted to acrylate-like surface compounds that are stabilized on the support (spillover of carbon-oxygen particles). Ethylene is polymerized in such a system.
Cite:
Davydov A.A.
IR Spectroscopic Study of Hydrocarbon Adsorption on Oxide Catalysts. XVI. Interaction of C3H6 and C2H4 with V2O5/Al2O3
Kinetics and Catalysis. 1990. V.31. N3 pt 2. P.571-577. WOS Scopus РИНЦ
IR Spectroscopic Study of Hydrocarbon Adsorption on Oxide Catalysts. XVI. Interaction of C3H6 and C2H4 with V2O5/Al2O3
Kinetics and Catalysis. 1990. V.31. N3 pt 2. P.571-577. WOS Scopus РИНЦ
Original:
Давыдов А.А.
Изучение адсорбции углеводородов на оксидных катализаторах методом ИК-спектроскопии. XVI. Взаимодействие C3H6 и C2H4 с V2O5/Al2O3
Кинетика и катализ. 1990. Т.31. №3. С.652-658. РИНЦ
Изучение адсорбции углеводородов на оксидных катализаторах методом ИК-спектроскопии. XVI. Взаимодействие C3H6 и C2H4 с V2O5/Al2O3
Кинетика и катализ. 1990. Т.31. №3. С.652-658. РИНЦ
Dates:
Submitted: | Jun 24, 1988 |
Published print: | Dec 1, 1990 |
Identifiers:
Web of science | WOS:A1990EY63900002 |
Scopus | 2-s2.0-0025540923 |
Elibrary | 31094771 |