The State and Catalytic Properties of (Pd+Ln)/SiO2 Prepared by Grafting of Organometallic Complexes on the Support Surface Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 1994, Volume: 35, Number: 1, Pages: 97-101 Pages count : 5 | ||||
Tags | LANTHANA-PROMOTED Rh/SiO2; PALLADIUM CATALYSTS; CO HYDROGENATION; Pd/SiO2; H-2; ADSORPTION; IONS; METHANOL; GAS | ||||
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Abstract:
It is found that the activity and selectivity of all bimetallic (Pd + Ln)/SiO2 systems toward methanol in the synthesis from CO and H-2 exceed those of Pd/SiO2. An opposite effect is observed in the propylene hydroformylation process. The assumption is proved that the hydroformylation of olefins occurs on monometallic palladium clusters without participation of the combined Pd-Ln(n+) sites and CO complexes activated on these sites.
Cite:
Koval'chuk V.I.
, Nogin Y.K.
, Chesnokov N.V.
, Ryndin Y.A.
, Kuznetsov B.N.
The State and Catalytic Properties of (Pd+Ln)/SiO2 Prepared by Grafting of Organometallic Complexes on the Support Surface
Kinetics and Catalysis. 1994. V.35. N1. P.97-101. WOS РИНЦ
The State and Catalytic Properties of (Pd+Ln)/SiO2 Prepared by Grafting of Organometallic Complexes on the Support Surface
Kinetics and Catalysis. 1994. V.35. N1. P.97-101. WOS РИНЦ
Original:
Ковальчук В.И.
, Ногин Ю.Н.
, Чесноков Н.В.
, Рындин Ю.А.
, Кузнецов Б.Н.
Состояние и каталитические свойства (Pd+Ln)/SiO2, полученных закреплением металлоорганических комплексов на поверхности носителя
Кинетика и катализ. 1994. Т.35. №1. С.110-115. РИНЦ
Состояние и каталитические свойства (Pd+Ln)/SiO2, полученных закреплением металлоорганических комплексов на поверхности носителя
Кинетика и катализ. 1994. Т.35. №1. С.110-115. РИНЦ
Dates:
Submitted: | Mar 23, 1993 |
Identifiers:
Web of science | WOS:A1994NE85400017 |
Elibrary | 30596738 |
Citing:
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