Osmium Compounds as Catalysts of Alkene Oxidation Full article
Conference |
The First Russian Conference on Cluster Chemistry 27 Jun - 1 Jul 1994 , Санкт-Петербург |
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Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 1995, Volume: 36, Number: 3, Pages: 293-296 Pages count : 4 | ||||
Tags | HYDROXYLATION; CARBONYLS; COMPLEXES; RUTHENIUM; CLUSTER | ||||
Authors |
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Affiliations |
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Abstract:
The catalytic activity of trinuclear osmium clusters (mu-H)(2)Os-3(CO)(10), (mu-H)Os-3(CO)(10)(mu-OH), (mu-H)Os-3(CO)(9)(PPh(3))(mu-OH), (mu-H)Os-3(CO)(10){mu-O=CNHC(CH3)CO(2)Bu-t)}, and Os-3(CO)(12) is studied in alkene oxidation reactions. Oxidants were oxygen donors, such as H2O2, tert-BuOOH, and N-methylmorpholine N-oxide. Osmium clusters are found to catalyze syn-hydroxylation at low temperatures and the oxidative destruction of alkenes at room temperature. Osmium tetroxide is an active catalytic species, which is formed by the destruction of clusters in the oxidative medium.
Cite:
Kholdeeva O.A.
, Kirin V.P.
, Maksakov V.A.
, Grigorʹev V.A.
Osmium Compounds as Catalysts of Alkene Oxidation
Kinetics and Catalysis. 1995. V.36. N3. P.293-296. WOS РИНЦ
Osmium Compounds as Catalysts of Alkene Oxidation
Kinetics and Catalysis. 1995. V.36. N3. P.293-296. WOS РИНЦ
Original:
Холдеева О.А.
, Кирин В.П.
, Максаков В.А.
, Григорьев В.А.
Осмиевые соединения как катализаторы реакций окисления алкенов
Кинетика и катализ. 1995. Т.36. №3. С.326-329. РИНЦ
Осмиевые соединения как катализаторы реакций окисления алкенов
Кинетика и катализ. 1995. Т.36. №3. С.326-329. РИНЦ
Dates:
Submitted: | Jul 1, 1994 |
Identifiers:
Web of science | WOS:A1995RJ73100002 |
Elibrary | 29283299 |
Chemical Abstracts | 1995:707457 |
Chemical Abstracts (print) | 123:198119 |