Nontrivial Mechanism of Heterogeneous Catalysis Observed in Liquid-Phase Hydrogenation of 6, 10, 14-Trimethylpentadeca-3,5-dien-2-one Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
||||
---|---|---|---|---|---|
Output data | Year: 1987, Volume: 33, Number: 2, Pages: 339-343 Pages count : 5 DOI: 10.1007/BF02128086 | ||||
Tags | Hydrogenation; Experimental Data; Physical Chemistry; Catalysis; Ketone | ||||
Authors |
|
||||
Affiliations |
|
Abstract:
The kinetics of selective hydrogenation of 6, 10, 14-trimethylpentadeca-4,5-dien-2-one (C-18 ketone) catalyzed by Pd/Al2O3 has revealed that the rate law for all steps is proportional to the 2–3rd power of the catalyst concentration. Experimental data and their mathematical description are presented. This effect has been discovered for the first time and needs theoretical interpretation to elaborate a detailed reaction mechanism.
Cite:
Sulman E.M.
, Yermakova A.
, Popov O.S.
Nontrivial Mechanism of Heterogeneous Catalysis Observed in Liquid-Phase Hydrogenation of 6, 10, 14-Trimethylpentadeca-3,5-dien-2-one
Reaction Kinetics and Catalysis Letters. 1987. V.33. N2. P.339-343. DOI: 10.1007/BF02128086 WOS Scopus РИНЦ
Nontrivial Mechanism of Heterogeneous Catalysis Observed in Liquid-Phase Hydrogenation of 6, 10, 14-Trimethylpentadeca-3,5-dien-2-one
Reaction Kinetics and Catalysis Letters. 1987. V.33. N2. P.339-343. DOI: 10.1007/BF02128086 WOS Scopus РИНЦ
Dates:
Submitted: | Jan 7, 1986 |
Accepted: | Jul 17, 1986 |
Published print: | Sep 1, 1987 |
Identifiers:
Web of science | WOS:A1987J504600016 |
Scopus | 2-s2.0-34250107733 |
Elibrary | 30981268 |
Chemical Abstracts | 1988:185980 |
Chemical Abstracts (print) | 108:185980 |
OpenAlex | W1983718800 |