EPR Study of the Nature of Active Sites and the Type of Their Deactivation in CO Hydrogenation on (Ni+Ti)/SiO2 Catalysts Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 1989, Volume: 38, Number: 2, Pages: 319-324 Pages count : 6 DOI: 10.1007/BF02062125 | ||
Tags | Oxidation; Hydrogenation; Physical Chemistry; Nickel; SiO2 | ||
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Abstract:
As shown by EPR, upon supporting Ni(π-C3H5)2 on Ti/SiO2, the Ni complex is coordinated to Ti3+ ions. Deactivation of (Ni+Ti)/SiO2 catalysts so obtained during CO hydrogenation is due to the oxidation of Ti3+ ions and metallic nickel particles by reaction products.
Cite:
Alekseev O.S.
, Poluboyarov V.A.
, Ryndin Y.A.
, Anufrienko V.F.
EPR Study of the Nature of Active Sites and the Type of Their Deactivation in CO Hydrogenation on (Ni+Ti)/SiO2 Catalysts
Reaction Kinetics and Catalysis Letters. 1989. V.38. N2. P.319-324. DOI: 10.1007/BF02062125 WOS Scopus РИНЦ
EPR Study of the Nature of Active Sites and the Type of Their Deactivation in CO Hydrogenation on (Ni+Ti)/SiO2 Catalysts
Reaction Kinetics and Catalysis Letters. 1989. V.38. N2. P.319-324. DOI: 10.1007/BF02062125 WOS Scopus РИНЦ
Dates:
Submitted: | Jun 10, 1988 |
Accepted: | Aug 11, 1988 |
Published print: | Sep 1, 1989 |
Identifiers:
Web of science | WOS:A1989T250200018 |
Scopus | 2-s2.0-34249970419 |
Elibrary | 30904547 |
Chemical Abstracts | 1989:180092 |
Chemical Abstracts (print) | 110:180092 |
OpenAlex | W2092236626 |