Kinetic Studies of Methylmercaptan Production from Dimethyl Sulfide and H2S Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 1992, Volume: 46, Number: 1, Pages: 187-192 Pages count : 6 DOI: 10.1007/BF02096696 | ||
Tags | Methyl; Physical Chemistry; Sulfide; Catalysis; Dimethyl; Alumina - Surface Properties; Catalysts - Activity; Chemical Reactions - Reaction Kinetics; Hydrogen Sulfide - Chemical Reactions | ||
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Abstract:
Kinetic regularities of methylmercaptan production from dimethyl sulfide and H2S in the presence of γ-Al2O3 have been studied under gradientless conditions. A stepwise reaction mechanism is suggested implying that the catalyst surface is methoxylated by methyl sulfide and then CH3O groups interact with H2S. The kinetic equation obtained describes fairly well this process on the nonhomogeneous catalyst surface.
Cite:
Mashkin V.Y.
, Koshelev S.N.
Kinetic Studies of Methylmercaptan Production from Dimethyl Sulfide and H2S
Reaction Kinetics and Catalysis Letters. 1992. V.46. N1. P.187-192. DOI: 10.1007/BF02096696 WOS Scopus РИНЦ
Kinetic Studies of Methylmercaptan Production from Dimethyl Sulfide and H2S
Reaction Kinetics and Catalysis Letters. 1992. V.46. N1. P.187-192. DOI: 10.1007/BF02096696 WOS Scopus РИНЦ
Dates:
Submitted: | May 11, 1991 |
Accepted: | Jun 25, 1991 |
Published print: | Jan 1, 1992 |
Identifiers:
Web of science | WOS:A1992HD87500028 |
Scopus | 2-s2.0-0026626638 |
Elibrary | 31071662 |
Chemical Abstracts | 1992:151073 |
Chemical Abstracts (print) | 116:151073 |
OpenAlex | W2038511923 |