Influence of Polarization of Nickel and Palladium Electrodes with Proton-Conducting Solid Electrolytes on the Catalytic Properties of These Electrodes in Ethylene Hydrogenation Full article
Journal |
Soviet Electrochemistry (1965-1992), after 1992 - Russian Electrochemistry
ISSN: 0038-5387 |
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Output data | Year: 1992, Volume: 28, Number: 10, Pages: 1200-1207 Pages count : 8 | ||
Tags | FARADAIC ELECTROCHEMICAL MODIFICATION; OXIDATION; PHASE | ||
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Abstract:
Ethylene hydrogenation was studied on Ni and Pt electrodes in cells with a proton-conducting solid electrolyte: C2H4 + H2, Ni(Pd) \ CsHSO4 \ Pd, He + H2. It was found that depending on the direction of current flow in the cell (or hydrogen flux in the electrolyte), it is possible to reversibly alter (lower or raise) the catalytic activity of the Ni electrode. The changes in ethylene hydrogenation rate were found to be of a nonfaradaic nature, and more than an order of magnitude in excess of the hydrogen flux in the electrolyte.
Cite:
Politova T.I.
, Sobyanin V.A.
, Belyaev V.D.
Influence of Polarization of Nickel and Palladium Electrodes with Proton-Conducting Solid Electrolytes on the Catalytic Properties of These Electrodes in Ethylene Hydrogenation
Soviet Electrochemistry (1965-1992), after 1992 - Russian Electrochemistry. 1992. V.28. N10. P.1200-1207. WOS РИНЦ
Influence of Polarization of Nickel and Palladium Electrodes with Proton-Conducting Solid Electrolytes on the Catalytic Properties of These Electrodes in Ethylene Hydrogenation
Soviet Electrochemistry (1965-1992), after 1992 - Russian Electrochemistry. 1992. V.28. N10. P.1200-1207. WOS РИНЦ
Original:
Политова Т.И.
, Собянин В.А.
, Беляев В.Д.
Влияние поляризации никелевого и палладиевого электродов, контактирующих с твердым протонпроводящим электролитом, на их каталитические свойства в отношении реакции гидрирования этилена
Электрохимия. 1992. Т.28. №10. С.1466-1475. РИНЦ
Влияние поляризации никелевого и палладиевого электродов, контактирующих с твердым протонпроводящим электролитом, на их каталитические свойства в отношении реакции гидрирования этилена
Электрохимия. 1992. Т.28. №10. С.1466-1475. РИНЦ
Dates:
Published print: | Oct 1, 1992 |
Identifiers:
Web of science | WOS:A1992LF93000007 |
Elibrary | 30782711 |
Citing:
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