Reaction of Anions of Original Salts with Products of Hydrolytic Polymerization of Al(III) Aquo Ions Full article
Journal |
Russian Chemical Bulletin
ISSN: 1066-5285 , E-ISSN: 1573-9171 |
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Output data | Year: 1977, Volume: 26, Number: 12, Pages: 2447-2450 Pages count : 4 DOI: 10.1007/BF00924541 | ||
Tags | Polymerization; Aluminum; Chloride; Nitrate; SO42 | ||
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Abstract:
Conclusions:
1. During polymerization of aquo ions of Al(III), nitrate and chloride ions take part in the formation of sol particles, forming two types of bond, strong and weak. The weakly held anions are in a state of rapid exchange with free anions of the solution.
2. The ClO4 − anion does not interact with the polymerization products of the aquo ions of aluminum.
3. The SO4 2− anion prevents the formation of hydroxo complex Al13O4 (OH)24 (H2O)12 7+ and promotes the formation of sol particles.
4. The broadening of the NMR lines of quadrupole nuclei in the anions and solvent is a sensitive indicator of the formation of sol particles in the solutions.
Cite:
Fedotov M.A.
, Krivoruchko O.P.
, Buyanov R.A.
Reaction of Anions of Original Salts with Products of Hydrolytic Polymerization of Al(III) Aquo Ions
Russian Chemical Bulletin. 1977. V.26. N12. P.2447-2450. DOI: 10.1007/BF00924541 WOS Scopus РИНЦ
Reaction of Anions of Original Salts with Products of Hydrolytic Polymerization of Al(III) Aquo Ions
Russian Chemical Bulletin. 1977. V.26. N12. P.2447-2450. DOI: 10.1007/BF00924541 WOS Scopus РИНЦ
Original:
Федотов М.А.
, Криворучко О.П.
, Буянов Р.А.
Взаимодействие ионов исходных солей с продуктами гидролитической полимеризации аква-ионов Al(III)
Известия Академии наук. Серия химическая. 1977. №12. С.2647-2651. РИНЦ
Взаимодействие ионов исходных солей с продуктами гидролитической полимеризации аква-ионов Al(III)
Известия Академии наук. Серия химическая. 1977. №12. С.2647-2651. РИНЦ
Dates:
Submitted: | Aug 9, 1976 |
Published print: | Dec 1, 1977 |
Identifiers:
Web of science | WOS:A1977FK47500001 |
Scopus | 2-s2.0-34250295319 |
Elibrary | 30917697 |
OpenAlex | W2061311950 |
Citing:
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