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Composite Mechanism of the Catalytic Hydrogenation of Unsaturated Hydrocarbons on Hydrided Magnesium Intermetallides Science article

Общее Language: Английский, Genre: Full article,
Status: Published, Source type: Translated
Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 2006, Volume: 47, Number: 5, Pages: 744-746 Pages count : 3 DOI: 10.1134/S0023158406050132
Authors Molchanov V.V. 1 , Goidin V.V. 1 , Buyanov R.A. 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia

Funding (2)

1 Council for Grants of the President of the Russian Federation НШ-2120.2003.3
2 Russian Foundation for Basic Research 02-03-32327

Abstract: Two temperature ranges are distinguished in the catalytic hydrogenation of unsaturated hydrocarbons on magnesium intermetallide hydrides. In the lower temperature range, the reaction proceeds by a composite mechanism, as is indicated by the fact that the rate of the catalytic hydrogenation of ethylene, n-butenes, and butadiene is equal to the rate of the reduction of these hydrocarbons with hydride hydrogen. It is assumed that, at higher temperatures, the reaction proceeds by a heterogeneous-homogeneous mechanism.
Cite: Molchanov V.V. , Goidin V.V. , Buyanov R.A.
Composite Mechanism of the Catalytic Hydrogenation of Unsaturated Hydrocarbons on Hydrided Magnesium Intermetallides
Kinetics and Catalysis. 2006. V.47. N5. P.744-746. DOI: 10.1134/S0023158406050132 WOS Scopus РИНЦ AN: 2006:1026900 CAN: 147:75349
article_link_type.translated_to_original: Молчанов В.В. , Гойдин В.В. , Буянов Р.А.
Стадийный механизм каталитического гидрирования ненасыщенных углеводородов на гидридах интерметаллидов магния
Кинетика и катализ. 2006. Т.47. №5. С.767-769. РИНЦ publication_identifier_short.rsci: RSCI:17307267
Dates:
Submitted: Jan 19, 2005
Published print: Sep 1, 2006
Identifiers:
Chemical Abstracts 2006:1026900
Chemical Abstracts (print) 147:75349
Web of science WOS:000241045200013
Scopus 2-s2.0-33749386766
Rinz 13522083
Links:
  • Web of science - publication.cite_link
  • Scopus - publication.cite_link
  • Rinz - publication.cite_link
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