Transformation of n-Hexane on Al2O3 and SiO2 Supported Pt, Pt+Ga and Ir+Pt+Ga Catalysts Prepared by Anchoring Methods Full article
Journal |
Reaction Kinetics and Catalysis Letters
ISSN: 0133-1736 , E-ISSN: 1588-2837 |
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Output data | Year: 2006, Volume: 87, Number: 2, Pages: 313-324 Pages count : 12 DOI: 10.1007/s11144-006-0039-x | ||||
Tags | Aromatization, Catalyst, Hydrogenolysis, Ir+Pt+Ga/Al 2O3, Ir+Pt+Ga/SiO2, n-Hexane, Pt+Ga/Al2O3, Pt+Ga/SiO2 | ||||
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Abstract:
Transformation of n-hexane over Al2O3 and SiO2 supported Pt, Pt+Ga and Ir+Pt+Ga catalysts was studied in a continuous-flow reactor operated under slug-pulse mode at 520°C. Bimetallic catalysts were prepared by introducing first Ga(OEt)3 and then diallylplatinum as precursor compounds. Iridium was then introduced via decomposition of Ir4(CO)12 adsorbed onto Pt+Ga catalysts. The addition of Ga to Pt/SiO2 catalyst decreased hydrogenation, aromatization and hydrogenolysis selectivity. Over Pt/Al2O3 catalyst Ga increased hydrogenolysis selectivity and decreased isomerization and C5-cyclization. The main effect of Ir was to increase hydrogenolysis selectivity and the stability of catalysts.
Cite:
Gőbölös S.
, Margitfalvi J.L.
, Hegedűs M.
, Ryndin Y.A.
Transformation of n-Hexane on Al2O3 and SiO2 Supported Pt, Pt+Ga and Ir+Pt+Ga Catalysts Prepared by Anchoring Methods
Reaction Kinetics and Catalysis Letters. 2006. V.87. N2. P.313-324. DOI: 10.1007/s11144-006-0039-x WOS Scopus РИНЦ
Transformation of n-Hexane on Al2O3 and SiO2 Supported Pt, Pt+Ga and Ir+Pt+Ga Catalysts Prepared by Anchoring Methods
Reaction Kinetics and Catalysis Letters. 2006. V.87. N2. P.313-324. DOI: 10.1007/s11144-006-0039-x WOS Scopus РИНЦ
Dates:
Submitted: | Nov 21, 2005 |
Accepted: | Nov 30, 2005 |
Published print: | Apr 1, 2006 |
Identifiers:
Web of science | WOS:000236239300013 |
Scopus | 2-s2.0-33244456375 |
Elibrary | 13521101 |
Chemical Abstracts | 2006:169310 |
Chemical Abstracts (print) | 145:148522 |
OpenAlex | W2324266373 |