Catalytic Activity of Systems Based on Titanium Bis(phenoxy Imine) Complexes: Effect of the Ligand Structure Full article
Journal |
Russian Journal of Applied Chemistry
ISSN: 1070-4272 , E-ISSN: 1608-3296 |
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Output data | Year: 2007, Volume: 80, Number: 9, Pages: 1515-1522 Pages count : 8 DOI: 10.1134/S1070427207090145 | ||||
Tags | Catalytic Activity; Catalytic System; Phenoxy; Bulky Substituent; Phenoxy Group | ||||
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Abstract:
Polymerization of ethylene at 30–70°C in the presence of catalytic systems based on titanium bis(phenoxy imine) complexes of various structures, activated with methylalumoxane, was studied. An attempt was made to systematize the effect of substituents in ligands, to find correlations, to account for the results obtained, and to reveal conditions under which the reaction occurs by the living polymerization mechanism. Some properties and structural features of the polyethylenes obtained were determined.
Cite:
Malinskaya M.Y.
, Ivancheva N.I.
, Oleinik I.I.
, Tolstikov G.A.
, Ivanchev S.S.
Catalytic Activity of Systems Based on Titanium Bis(phenoxy Imine) Complexes: Effect of the Ligand Structure
Russian Journal of Applied Chemistry. 2007. V.80. N9. P.1515-1522. DOI: 10.1134/S1070427207090145 WOS Scopus РИНЦ
Catalytic Activity of Systems Based on Titanium Bis(phenoxy Imine) Complexes: Effect of the Ligand Structure
Russian Journal of Applied Chemistry. 2007. V.80. N9. P.1515-1522. DOI: 10.1134/S1070427207090145 WOS Scopus РИНЦ
Original:
Малинская М.Ю.
, Иванчева Н.И.
, Олейник И.И.
, Толстиков Г.А.
, Иванчев С.С.
Влияние строения лигандов бис(феноксииминных) комплексов титана на активность каталитических систем на их основе
Журнал прикладной химии. 2007. Т.80. №9. С.1479-1488. РИНЦ
Влияние строения лигандов бис(феноксииминных) комплексов титана на активность каталитических систем на их основе
Журнал прикладной химии. 2007. Т.80. №9. С.1479-1488. РИНЦ
Dates:
Submitted: | Jul 22, 2007 |
Published print: | Sep 1, 2007 |
Identifiers:
Web of science | WOS:000250622800014 |
Scopus | 2-s2.0-35448957742 |
Elibrary | 13540394 |
Chemical Abstracts | 2007:1250757 |
Chemical Abstracts (print) | 150:56577 |
OpenAlex | W2000568502 |