Radiation Grafting of Vinylalkoxysilanes onto Polypropylene Full article
Journal |
Polymer Science Series A
ISSN: 0965-545X , E-ISSN: 1555-6107 |
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Output data | Year: 2001, Volume: 43, Number: 5, Pages: 490-494 Pages count : 5 | ||||||
Tags | Acrylic monomers; Diffusion; Hydrolysis; Irradiation; Polypropylenes; Silicon compounds | ||||||
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Abstract:
The process of radiation grafting of vinylalkoxysilanes, monomers inactive in free-radical polymerization, onto PP was studied. The effects of the chemical structure of vinylalkoxysilanes and their sorption-diffusion characteristics, as well as irradiation parameters on the efficiency of radiation grafting were assessed. Based on the data obtained, the experimental conditions which make it possible to exclude the diffusion control of the process were determined. It was shown that the hydrolysis of alkoxy groups of vinylsilanes radiation-grafted onto PP provides a means of obtaining structured PP with a desired content of gel fraction.
Cite:
Ivanchev S.S.
, Rätzsch M.
, Mesh A.M.
, Khaikin S.Y.
, Bucka H.
, Hesse A.
Radiation Grafting of Vinylalkoxysilanes onto Polypropylene
Polymer Science Series A. 2001. V.43. N5. P.490-494. WOS Scopus РИНЦ
Radiation Grafting of Vinylalkoxysilanes onto Polypropylene
Polymer Science Series A. 2001. V.43. N5. P.490-494. WOS Scopus РИНЦ
Original:
Иванчев С.С.
, Rätzsch M.
, Меш А.М.
, Хайкин С.Я.
, Bucka H.
, Hesse A.
Особенности радиационной прививки винилалкоксисиланов к полипропилену
Высокомолекулярные соединения. Серия А. 2001. Т.43. №5. С.793-798. Scopus РИНЦ
Особенности радиационной прививки винилалкоксисиланов к полипропилену
Высокомолекулярные соединения. Серия А. 2001. Т.43. №5. С.793-798. Scopus РИНЦ
Dates:
Submitted: | Oct 25, 2000 |
Published print: | May 1, 2001 |
Identifiers:
Web of science | WOS:000168954200003 |
Scopus | 2-s2.0-0035343260 |
Elibrary | 13363627 |