Kinetics of Isotopic Exchange between Gaseous Hydrogen and Hydrogen Desolved in Palladium Full article
Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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Output data | Year: 1966, Volume: 7, Number: 3, Pages: 416-419 Pages count : 4 | ||
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Abstract:
The effect of temp. and pressure on the rate of isotope exchange and the sepn. coeff. was studied for the system H-H dissolved in Pd. In the temp. range at -20 to 100В° the isotope exchange is characterized by const. values of the heat of reaction (1080 cal./mole) and energy of activation of the exchange reaction (7270 cal./mole). The rate const. of the isotope exchange reaction increases linearly with an increase in H pressure over the Pd. At pressures <200 mm. Hg there is a sharp dependence of the sepn. coeff. on the H pressure.
Cite:
Andreev B.M.
, Boreskov G.K.
, Chang C.T.
, Tsionskii V.M.
Kinetics of Isotopic Exchange between Gaseous Hydrogen and Hydrogen Desolved in Palladium
Kinetics and Catalysis. 1966. V.7. N3. P.416-419. РИНЦ
Kinetics of Isotopic Exchange between Gaseous Hydrogen and Hydrogen Desolved in Palladium
Kinetics and Catalysis. 1966. V.7. N3. P.416-419. РИНЦ
Original:
Андреев Б.М.
, Боресков Г.К.
, Чжэн Ч-ц.
, Ционский В.М.
Кинетика изотопного обмена между газообразным водородом и водородом, растворенным в палладии
Кинетика и катализ. 1966. Т.7. №3. С.470-474. РИНЦ
Кинетика изотопного обмена между газообразным водородом и водородом, растворенным в палладии
Кинетика и катализ. 1966. Т.7. №3. С.470-474. РИНЦ
Identifiers:
Elibrary | 28857989 |
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