Aqueous Phase Reforming of Xylitol over Mono- and Bimetallic Carbonsupported Catalysts
Conference theses
Общее |
Language:
Английский,
Genre:
Conference Abstracts,
Status:
Published,
Source type:
Original
|
Conference |
XII European Congress on Catalysis “Catalysis: Balancing the use of fossil and renewable resources” (EuropaCat-XII)
30 Aug - 4 Sep 2015
,
Казань
|
Source |
EuropaCat XII. Catalysis: Balancing the use of fossil and renewable resources. XII European Congress on Catalysis, Kazan (Russia), 30 August - 4 September, 2015 : Book of Abstracts
Compilation,
Boreskov Institute of Catalysis. Novosibirsk.2015.
2184 c. ISBN 9785906376107.
РИНЦ
|
Output data |
Year: 2015,
Pages: 200-201
Pages count
: 2
|
Authors |
Godina L.I.
1
,
Kirilin A.V.
1
,
Tokarev A.V.
1
,
Demidova Y.S.
2,3
,
Lemus J.
4
,
Calvo L.
4
,
Schubert T.
5
,
Gilarranz M.A.
4
,
Simakova I.L.
2,3
,
Murzin D.Y.
1
|
Affiliations |
1 |
Åbo Akademi University, Laboratory of Industrial Chemistry and Reaction Engineering, Åbo, Finland
|
2 |
Boreskov Institute of Catalysis SB RAS, Novosibirsk, Russia
|
3 |
Novosibirsk State University, Novosibirsk, Russia
|
4 |
Universidad Autónoma de Madrid, Madrid, Spain
|
5 |
FutureCarbon GmbH, Bayreuth, Germany
|
|
Funding (1)
1
|
European Commission
|
310490 FP7-NMP-2012-SMALL-6 SUSFUELCAT
|
Aqueous phase reforming is an advantageous technology, which allows hydrogen and alkanes production from carbohydrates obtained from abundant biomass sources. This process is beneficially compared with steam reforming, since aqueous solutions of feedstock are converted at moderate temperatures (190-250°C) and slightly elevated pressures, keeping the reaction in a liquid phase. Thus, less energy is spent for heating, no evaporation is needed, and undesirable reactions of coke formation are suppressed. The catalysts used for the APR process should have high hydrothermal stability, which determines the choice of carbon as the support material. In the current study metal screening is performed for different carbon-supported catalysts. The following issues are discussed: activity for xylitol conversion, selectivity to hydrogen and alkanes, and stability in long-term experiments.